Consider two initially separate metal blocks of aluminium (M, = 26.98 g/mol) and lead (Mr = 207.19 g/mol) in a chamber with adiabatic walls. The lead block of mass 3 g is initially at 100°C and that of aluminium of mass 4 g is initially at 25°C. The blocks are then placed in contact and allowed to thermally equilibrate. The molar heat capacities of the metals are considered constant over the temperature of experiment. At 1 bar, Cpm (Al) = 24.35 JK¹¹mol-¹ and Cp,m(Pb) = 26.44 JK¹mol-¹ Calculate a. b. C. the final temperature. the change in the entropy of the blocks in contact. identify evidence that the process occurred spontaneously or not.

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Consider two initially separate metal blocks of aluminium (M, = 26.98 g/mol) and lead
(Mr = 207.19 g/mol) in a chamber with adiabatic walls. The lead block of mass 3 g is initially
at 100°C and that of aluminium of mass 4 g is initially at 25°C. The blocks are then placed in
contact and allowed to thermally equilibrate. The molar heat capacities of the metals are
considered constant over the temperature of experiment. At 1 bar, Cp,m (Al) = 24.35 JK-¹mol-¹
and Cp,m(Pb) = 26.44 JK¹mol-¹
Calculate
a.
b.
C.
the final temperature.
the change in the entropy of the blocks in contact.
identify evidence that the process occurred spontaneously or not.
Transcribed Image Text:Consider two initially separate metal blocks of aluminium (M, = 26.98 g/mol) and lead (Mr = 207.19 g/mol) in a chamber with adiabatic walls. The lead block of mass 3 g is initially at 100°C and that of aluminium of mass 4 g is initially at 25°C. The blocks are then placed in contact and allowed to thermally equilibrate. The molar heat capacities of the metals are considered constant over the temperature of experiment. At 1 bar, Cp,m (Al) = 24.35 JK-¹mol-¹ and Cp,m(Pb) = 26.44 JK¹mol-¹ Calculate a. b. C. the final temperature. the change in the entropy of the blocks in contact. identify evidence that the process occurred spontaneously or not.
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