Consider the titration of 25.0 mL of 0.0100 M Sn²+ by 0.0500 M TI³* in 1M HCl using Pt and an SCE reference electrode to find the endpoint. Find E at the equivalence point. The titration reaction is: Sn²+ + Tl³+ → Sn*+ + Tl* When 25.00 mL of unknown were passed through a Jones reductor, molybdate ion (Mo0?-) was converted to Mo3+ according to the reaction Mo0?- + 8H* + 3e¯ → Mo3+ + 4H20. The filtrate required 16.43 mL of 0.01033 M KMN0, to reach the purple endpoint 3MN0, + 5M03+ + 4H* → 3MN²+ + 5 Mo03+ + 2H,0. A blank required 0.04 mL. Find the molarity in the unknown.
Consider the titration of 25.0 mL of 0.0100 M Sn²+ by 0.0500 M TI³* in 1M HCl using Pt and an SCE reference electrode to find the endpoint. Find E at the equivalence point. The titration reaction is: Sn²+ + Tl³+ → Sn*+ + Tl* When 25.00 mL of unknown were passed through a Jones reductor, molybdate ion (Mo0?-) was converted to Mo3+ according to the reaction Mo0?- + 8H* + 3e¯ → Mo3+ + 4H20. The filtrate required 16.43 mL of 0.01033 M KMN0, to reach the purple endpoint 3MN0, + 5M03+ + 4H* → 3MN²+ + 5 Mo03+ + 2H,0. A blank required 0.04 mL. Find the molarity in the unknown.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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