Consider the titration of 25.0 mL of 0.0100 M Sn²+ by 0.0500 M TI³* in 1M HCl using Pt and an SCE reference electrode to find the endpoint. Find E at the equivalence point. The titration reaction is: Sn²+ + Tl³+ → Sn*+ + Tl* When 25.00 mL of unknown were passed through a Jones reductor, molybdate ion (Mo0?-) was converted to Mo3+ according to the reaction Mo0?- + 8H* + 3e¯ → Mo3+ + 4H20. The filtrate required 16.43 mL of 0.01033 M KMN0, to reach the purple endpoint 3MN0, + 5M03+ + 4H* → 3MN²+ + 5 Mo03+ + 2H,0. A blank required 0.04 mL. Find the molarity in the unknown.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Consider the titration of 25.0 mL of 0.0100 M Sn²+ by 0.0500 M TI³* in 1M HCl
using Pt and an SCE reference electrode to find the endpoint. Find E at the
equivalence point. The titration reaction is: Sn²+ + Tl³+ → Sn*+ + Tl*
When 25.00 mL of unknown were passed through a Jones reductor, molybdate ion
(Mo0?-) was converted to Mo3+ according to the reaction Mo0?- + 8H* + 3e¯ →
Mo3+ + 4H20. The filtrate required 16.43 mL of 0.01033 M KMN0, to reach the
purple endpoint 3MN0, + 5M03+ + 4H* → 3MN²+ + 5 Mo03+ + 2H,0. A blank
required 0.04 mL. Find the molarity in the unknown.
Transcribed Image Text:Consider the titration of 25.0 mL of 0.0100 M Sn²+ by 0.0500 M TI³* in 1M HCl using Pt and an SCE reference electrode to find the endpoint. Find E at the equivalence point. The titration reaction is: Sn²+ + Tl³+ → Sn*+ + Tl* When 25.00 mL of unknown were passed through a Jones reductor, molybdate ion (Mo0?-) was converted to Mo3+ according to the reaction Mo0?- + 8H* + 3e¯ → Mo3+ + 4H20. The filtrate required 16.43 mL of 0.01033 M KMN0, to reach the purple endpoint 3MN0, + 5M03+ + 4H* → 3MN²+ + 5 Mo03+ + 2H,0. A blank required 0.04 mL. Find the molarity in the unknown.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Electroanalytical Techniques
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY