Consider the titration of 100.0 mL of 0.010 0 M Ce4+ in 1 M HClO4 by 0.040 0 M Cu+ to give Ce3+ and Cu2+, using Pt and Ag | AgCl electrodes (Eref = 0.197 V) to find the end point.Ce4+ + e- ↔ Ce3+ E⁰ = 1.70Cu2+ + e- ↔ Cu+ E⁰ = 0.161Calculate E at the following volumes of Cu+: 12.5, 25.0, and 30.0 mL.

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Answered: Consider the titration of 100.0 mL of…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Consider the titration of 100.0 mL of 0.010 0 M Ce⁴⁺ in 1 M HClO₄ by 0.040 0 M Cu⁺ to give Ce³⁺ and Cu²⁺, using Pt and Ag | AgCl electrodes (E_ref = 0.197 V) to find the end point.

Ce⁴⁺ + e- ↔ Ce³⁺ E⁰ = 1.70

Cu²⁺ + e- ↔ Cu⁺ E⁰ = 0.161

Calculate E at the following volumes of Cu⁺: 12.5, 25.0, and 30.0 mL.

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