Consider the table of the standard electrode potentials at 25 °C: Reduction half-reaction E° (V) Au³+(aq) + 3e¯ → Au(s) 1.50 I03 (aq) + 6H*(aq) + 5e¯ →I2(aq) + 3H2O(1) 1.20 2H+(aq) + 2e → H2(g) Cr³+(aq) + 3e¯ → Cr(s) -0.73

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Consider the table of the standard electrode potentials at 25 °C:
Reduction half-reaction
E° (V)
Au
13+ (aq) + 3e¯ → Au(s)
1.50
I03 (aq) + 6H*(aq) + 5e¯ → I2(aq) + 3H2O(1)
1.20
2H+(aq) + 2e → H2(g)
Cr³+ (aq) + 3e → Cr(s)
-0.73
Transcribed Image Text:Consider the table of the standard electrode potentials at 25 °C: Reduction half-reaction E° (V) Au 13+ (aq) + 3e¯ → Au(s) 1.50 I03 (aq) + 6H*(aq) + 5e¯ → I2(aq) + 3H2O(1) 1.20 2H+(aq) + 2e → H2(g) Cr³+ (aq) + 3e → Cr(s) -0.73
Identify whether Au or Cr or both or neither will dissolve in 1 M HIO3 .
Both Au and Cr will dissolve.
Only Cr will dissolve.
Only Au will dissolve.
Neither Au nor Cr will dissolve.
Submit
Previous Answers
Correct
HIO3 oxidizes metals through the following reduction half-reaction:
I03 (aq) + 6H*(aq) + 5e →I2(aq) + 3H2O(1)
Because this half-reaction is above the reduction of H+ in the table, HIO3 can oxidize
some metals (for example, copper or silver) that cannot be oxidized by HCl. In general,
the metals with reduction half-reactions listed below the reduction of IO3- to I2 in the
table dissolve in HIO3 , whereas the metals listed above it do not. Therefore, Au
(which has a reduction potential of 1.50 V) will not be oxidized, but Cr (which has a
reduction potential of –0.73 V) will be oxidized by both HCl and HIO3 .
Part B
Enter a balanced redox equation for the reaction that occurs.
Express your answer as a balanced net ionic equation including phases.
ΑΣφ
Transcribed Image Text:Identify whether Au or Cr or both or neither will dissolve in 1 M HIO3 . Both Au and Cr will dissolve. Only Cr will dissolve. Only Au will dissolve. Neither Au nor Cr will dissolve. Submit Previous Answers Correct HIO3 oxidizes metals through the following reduction half-reaction: I03 (aq) + 6H*(aq) + 5e →I2(aq) + 3H2O(1) Because this half-reaction is above the reduction of H+ in the table, HIO3 can oxidize some metals (for example, copper or silver) that cannot be oxidized by HCl. In general, the metals with reduction half-reactions listed below the reduction of IO3- to I2 in the table dissolve in HIO3 , whereas the metals listed above it do not. Therefore, Au (which has a reduction potential of 1.50 V) will not be oxidized, but Cr (which has a reduction potential of –0.73 V) will be oxidized by both HCl and HIO3 . Part B Enter a balanced redox equation for the reaction that occurs. Express your answer as a balanced net ionic equation including phases. ΑΣφ
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