Consider the reaction of ammonium ions (NH4) and nitrite ions (NO2 ), shown in Equation 19. (Eq. 19) NH, (aq) + NO, (aq) N2(g) + 2H2O(1) Solutions containing NH4* and NO2 were mixed in various quantities and the following rate data at a constant temperature were obtained: Initial rate for formation of N2, mol/L s Determination Initial NH4" concentration, mol/L Initial NO2 питber concentration, mol/L 3.04 x 10-7 0.150 7.50 x 10 3 6.08 x 10 0.150 1.50 x 10 2 6. 1.22 x 10 0.300 1.50 x 10 2 ) Use the method of initial rates to find the order of the reaction with respect to NH4 . ) Use the method of initial rates to find the order of the reaction with respect to NO2 . No the Calculate the rate constant, k, for the reaction of NH4 and NO,. Write the rate equation for the reaction of NH4 and NO2. 123

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Consider the reaction of ammonium ions (NH4) and nitrite ions (NO2 ), shown in Equation 19.
(Eq. 19)
NH, (aq) + NO, (aq) N2(g) + 2H2O(1)
Solutions containing NH4* and NO2 were mixed in various quantities and the following rate data at
a constant temperature were obtained:
Initial rate for formation of
N2, mol/L s
Determination
Initial NH4"
concentration, mol/L
Initial NO2
питber
concentration, mol/L
3.04 x 10-7
0.150
7.50 x 10 3
6.08 x 10
0.150
1.50 x 10 2
6.
1.22 x 10
0.300
1.50 x 10 2
) Use the method of initial rates to find the order of the reaction with respect to NH4 .
) Use the method of initial rates to find the order of the reaction with respect to NO2 .
No
the
Calculate the rate constant, k, for the reaction of NH4 and NO,.
Write the rate equation for the reaction of NH4 and NO2.
123
Transcribed Image Text:Consider the reaction of ammonium ions (NH4) and nitrite ions (NO2 ), shown in Equation 19. (Eq. 19) NH, (aq) + NO, (aq) N2(g) + 2H2O(1) Solutions containing NH4* and NO2 were mixed in various quantities and the following rate data at a constant temperature were obtained: Initial rate for formation of N2, mol/L s Determination Initial NH4" concentration, mol/L Initial NO2 питber concentration, mol/L 3.04 x 10-7 0.150 7.50 x 10 3 6.08 x 10 0.150 1.50 x 10 2 6. 1.22 x 10 0.300 1.50 x 10 2 ) Use the method of initial rates to find the order of the reaction with respect to NH4 . ) Use the method of initial rates to find the order of the reaction with respect to NO2 . No the Calculate the rate constant, k, for the reaction of NH4 and NO,. Write the rate equation for the reaction of NH4 and NO2. 123
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