Consider the reaction CS2 (g) + 4H2 (g) = CH4 (9) + 2H,S(g) a. Calculate AH°,AS°, and AG° at 25°C for this reaction. AH; (kJ/mol) S° (J/mol·K) CS2 (g) 116.9 237.9 130.6 H2 (9) CH4 (9) -74.87 186.1 H,S(g) -20.50 205.6 ΔΗ. kJ AS° = J/K AG° kJ b. Assume AH° and ASº are constant with respect to a change of temperature. Now calculate AG° at 250°C. AG kJ %3D c. Compare the two values of AG°. What can you say about the spontaneity of the reaction at 25°C and at 250°C? The reaction will be spontaneous at 25°C, and it will be nonspontaneous at 250°C. The reaction will be nonspontaneous at 25°C, and it will be spontaneous at 250°C. The reaction will be spontaneous at both 25°C and 250°C. The reaction will be nonspontaneous at both 25°C and 250°C.

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Consider the reaction
CS2 (g) + 4H2 (g) = CH4(g) + 2H,S(g)
a. Calculate AH°,AS°,and AG° at 25°C for this reaction.
AH; (kJ/mol) S° (J/mol·K)
CS2 (g)
H2 (g)
CH4 (g)
116.9
237.9
130.6
-74.87
186.1
H2 S(g)
-20.50
205.6
ΔΗ'
kJ
AS° =
J/K
AG°
kJ
b. Assume AH° and AS° are constant with respect to a change of temperature. Now calculate AG° at 250°C.
AG
kJ
c. Compare the two values of AG°. What can you say about the spontaneity of the reaction at 25°C and at 250°C?
The reaction will be spontaneous at 25°C, and it will be nonspontaneous at 250°C.
The reaction will be nonspontaneous at 25°C, and it will be spontaneous at 250°C.
The reaction will be spontaneous at both 25°C and 250°C.
The reaction will be nonspontaneous at both 25°C and 250°C.
Transcribed Image Text:Consider the reaction CS2 (g) + 4H2 (g) = CH4(g) + 2H,S(g) a. Calculate AH°,AS°,and AG° at 25°C for this reaction. AH; (kJ/mol) S° (J/mol·K) CS2 (g) H2 (g) CH4 (g) 116.9 237.9 130.6 -74.87 186.1 H2 S(g) -20.50 205.6 ΔΗ' kJ AS° = J/K AG° kJ b. Assume AH° and AS° are constant with respect to a change of temperature. Now calculate AG° at 250°C. AG kJ c. Compare the two values of AG°. What can you say about the spontaneity of the reaction at 25°C and at 250°C? The reaction will be spontaneous at 25°C, and it will be nonspontaneous at 250°C. The reaction will be nonspontaneous at 25°C, and it will be spontaneous at 250°C. The reaction will be spontaneous at both 25°C and 250°C. The reaction will be nonspontaneous at both 25°C and 250°C.
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