Consider the reaction : 3A + 2B → 4CInitially, and at some fixed temperature, the reaction proceeds at such a rate that 2.3 millimoles of A are consumed in 1 minute and 12 secondes. The reaction takes place in 1 L.The following table contains the experimental data for the reaction. (Taken from Ball. Physical Chemistry, 2nd edition, 2006)Rate (M/s)[A], M[B], M1.081 x 10-50.6601.236.577 x 10-54.011.236.568 x 10-54.012.25 d. What is the order of the reaction.e. Express the rate law and the integrated form equation. Is the reaction elementary?f. If the rate constant k = 1.61x10-5s-1 and [A0] = 4M, find the period of time between the 12th and 13th half-life. *g. If, for the same reaction, at the same temperature, we were to add a catalyst, would Ea, A, k and v be larger, smaller or equal? Explain.

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

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Consider the reaction : 3A + 2B → 4C

Initially, and at some fixed temperature, the reaction proceeds at such a rate that 2.3 millimoles of A are consumed in 1 minute and 12 secondes. The reaction takes place in 1 L.

The following table contains the experimental data for the reaction. (Taken from Ball. Physical Chemistry, 2^ndedition, 2006)

Rate (M/s)	[A], M	[B], M
1.081 x 10^-5	0.660	1.23
6.577 x 10^-5	4.01	1.23
6.568 x 10^-5	4.01	2.25

d. What is the order of the reaction.

e. Express the rate law and the integrated form equation. Is the reaction elementary?

f. If the rate constant k = 1.61x10^-5s^-1and [A₀] = 4M, find the period of time between the 12^th and 13^thhalf-life.

*g. If, for the same reaction, at the same temperature, we were to add a catalyst, would E_a, A, k and v be larger, smaller or equal? Explain.

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