Consider the reaction2POCl3 (g) → 2PCl3 (g) +O2 (g)a. Calculate ΔG° for this reaction. The ΔG°f values for POCl3(g) and PCl3(g) are -502 kJ/mol and -270. kJ/mol,respectively.b. Is this reaction spontaneous under standard conditions at 298 K?c. The value of 6S' for this reaction is 179 J/K mol .At what temperaturesis this reaction spontaneous at standard conditions? Assume that ΔH°and ΔS°' do not depend on temperature.
Consider the reaction2POCl3 (g) → 2PCl3 (g) +O2 (g)a. Calculate ΔG° for this reaction. The ΔG°f values for POCl3(g) and PCl3(g) are -502 kJ/mol and -270. kJ/mol,respectively.b. Is this reaction spontaneous under standard conditions at 298 K?c. The value of 6S' for this reaction is 179 J/K mol .At what temperaturesis this reaction spontaneous at standard conditions? Assume that ΔH°and ΔS°' do not depend on temperature.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Consider the reaction
2POCl3 (g) → 2PCl3 (g) +O2 (g)
a. Calculate ΔG° for this reaction. The ΔG°f values for POCl3(g) and PCl3(g) are -502 kJ/mol and -270. kJ/mol,respectively.
b. Is this reaction spontaneous under standard conditions at 298 K?
c. The value of 6S' for this reaction is 179 J/K mol .At what temperatures
is this reaction spontaneous at standard conditions? Assume that ΔH°
and ΔS°' do not depend on temperature.
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