Consider the phase diagram of CO2 given below to answer the following questions: р 73,8 bar 5,2 bar 1,013 bar 194,7 K 216,6 K (-78,5 °C) (-56,6 °C) T 304,1 K (+31,0 °C) a) Fill in the blanks and label the respective phases (i.e. s, I, g and sc). b) Name the lines I, II and III in the diagram. What does it mean when a point lies on one of these lines? What happens when your system crosses the lines I, II, and III? c) Which phase transition(s) can CO2 undergo at a pressure of 1 atm? Give the approximate transition temperature(s). d) Name the two indicated points at (5.2 bar / 216.6 K) and (73.8 bar/304.1 K). What are the characteristics of these specific points? e) State Gibbs phase rule and determine the number of degrees of freedom for i) a point within one of the phases, ii) a point on one of the lines and iii) at the specific point at (5.2 bar / 216.6 K).

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Chapter1: Chemical Foundations
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Consider the phase diagram of CO2 given below to answer the following questions:
р
73,8 bar
5,2 bar
1,013 bar
194,7 K 216,6 K
(-78,5 °C) (-56,6 °C)
T
304,1 K
(+31,0 °C)
a) Fill in the blanks and label the respective phases (i.e. s, I, g and sc).
b) Name the lines I, II and III in the diagram. What does it mean when a point lies on
one of these lines? What happens when your system crosses the lines I, II, and III?
c) Which phase transition(s) can CO2 undergo at a pressure of 1 atm? Give the
approximate transition temperature(s).
d) Name the two indicated points at (5.2 bar/216.6 K) and (73.8 bar/304.1 K). What
are the characteristics of these specific points?
e) State Gibbs phase rule and determine the number of degrees of freedom for i) a
point within one of the phases, ii) a point on one of the lines and iii) at the specific
point at (5.2 bar/216.6 K).
Transcribed Image Text:Consider the phase diagram of CO2 given below to answer the following questions: р 73,8 bar 5,2 bar 1,013 bar 194,7 K 216,6 K (-78,5 °C) (-56,6 °C) T 304,1 K (+31,0 °C) a) Fill in the blanks and label the respective phases (i.e. s, I, g and sc). b) Name the lines I, II and III in the diagram. What does it mean when a point lies on one of these lines? What happens when your system crosses the lines I, II, and III? c) Which phase transition(s) can CO2 undergo at a pressure of 1 atm? Give the approximate transition temperature(s). d) Name the two indicated points at (5.2 bar/216.6 K) and (73.8 bar/304.1 K). What are the characteristics of these specific points? e) State Gibbs phase rule and determine the number of degrees of freedom for i) a point within one of the phases, ii) a point on one of the lines and iii) at the specific point at (5.2 bar/216.6 K).
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