Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest). Op _лp A) 1₂+ < 1₂ <1₂ B) 1₂¯ < 1₂ <1₂+ C) 12 <1₂ < 1₂+ D) 12¯ < 1₂+ < 12 -лp ор Os Ap .Jp
Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest). Op _лp A) 1₂+ < 1₂ <1₂ B) 1₂¯ < 1₂ <1₂+ C) 12 <1₂ < 1₂+ D) 12¯ < 1₂+ < 12 -лp ор Os Ap .Jp
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Molecular Orbital (MO) Diagrams and Bond Dissociation Energy
**Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest).**
#### MO Energy Levels Diagram:
- **σ*₂p** (Anti-bonding molecular orbital for 2p orbitals)
- **π*₂p**
- **π*₂p** (Degenerate anti-bonding molecular orbitals for 2p orbitals)
- **σ₂p** (Bonding molecular orbital for 2p orbitals)
- **π₂p**, **π₂p** (Degenerate bonding molecular orbitals for 2p orbitals)
- **σ*₂s** (Anti-bonding molecular orbital for 2s orbitals)
- **σ₂s** (Bonding molecular orbital for 2s orbitals)
#### Answer Options:
A) \(I_2^+ < I_2 < I_2^-\)
B) \(I_2^- < I_2 < I_2^+\)
C) \(I_2 < I_2^- < I_2^+\)
D) \(I_2^- < I_2^+ < I_2\)
### Explanation of the MO Diagram:
The diagram shows the molecular orbitals for diatomic species, ranging from lower energy bonding orbitals to higher energy anti-bonding orbitals. The bond dissociation energy is influenced by the number of electrons in bonding and anti-bonding orbitals; more electrons in bonding orbitals typically mean a stronger bond, while more electrons in anti-bonding orbitals weaken the bond.
### Question:
Identify the correct ranking of the bond dissociation energies for the given diatomic iodine species (\(I_2, I_2^+, I_2^-\)).
Select the correct option from the list above based on your understanding of the bond formation and dissociation energy principles.
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