Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest). Op _лp A) 1₂+ < 1₂ <1₂ B) 1₂¯ < 1₂ <1₂+ C) 12 <1₂ < 1₂+ D) 12¯ < 1₂+ < 12 -лp ор Os Ap .Jp

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

Thank you! Will leave good rating :)

### Molecular Orbital (MO) Diagrams and Bond Dissociation Energy

**Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest).**

#### MO Energy Levels Diagram:

- **σ*₂p** (Anti-bonding molecular orbital for 2p orbitals)
- **π*₂p**
- **π*₂p** (Degenerate anti-bonding molecular orbitals for 2p orbitals)
- **σ₂p** (Bonding molecular orbital for 2p orbitals)
- **π₂p**, **π₂p** (Degenerate bonding molecular orbitals for 2p orbitals)
- **σ*₂s** (Anti-bonding molecular orbital for 2s orbitals)
- **σ₂s** (Bonding molecular orbital for 2s orbitals)

#### Answer Options:

A) \(I_2^+ < I_2 < I_2^-\)

B) \(I_2^- < I_2 < I_2^+\)

C) \(I_2 < I_2^- < I_2^+\)

D) \(I_2^- < I_2^+ < I_2\)

### Explanation of the MO Diagram:

The diagram shows the molecular orbitals for diatomic species, ranging from lower energy bonding orbitals to higher energy anti-bonding orbitals. The bond dissociation energy is influenced by the number of electrons in bonding and anti-bonding orbitals; more electrons in bonding orbitals typically mean a stronger bond, while more electrons in anti-bonding orbitals weaken the bond.

### Question:

Identify the correct ranking of the bond dissociation energies for the given diatomic iodine species (\(I_2, I_2^+, I_2^-\)). 

Select the correct option from the list above based on your understanding of the bond formation and dissociation energy principles.

---
Transcribed Image Text:### Molecular Orbital (MO) Diagrams and Bond Dissociation Energy **Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest).** #### MO Energy Levels Diagram: - **σ*₂p** (Anti-bonding molecular orbital for 2p orbitals) - **π*₂p** - **π*₂p** (Degenerate anti-bonding molecular orbitals for 2p orbitals) - **σ₂p** (Bonding molecular orbital for 2p orbitals) - **π₂p**, **π₂p** (Degenerate bonding molecular orbitals for 2p orbitals) - **σ*₂s** (Anti-bonding molecular orbital for 2s orbitals) - **σ₂s** (Bonding molecular orbital for 2s orbitals) #### Answer Options: A) \(I_2^+ < I_2 < I_2^-\) B) \(I_2^- < I_2 < I_2^+\) C) \(I_2 < I_2^- < I_2^+\) D) \(I_2^- < I_2^+ < I_2\) ### Explanation of the MO Diagram: The diagram shows the molecular orbitals for diatomic species, ranging from lower energy bonding orbitals to higher energy anti-bonding orbitals. The bond dissociation energy is influenced by the number of electrons in bonding and anti-bonding orbitals; more electrons in bonding orbitals typically mean a stronger bond, while more electrons in anti-bonding orbitals weaken the bond. ### Question: Identify the correct ranking of the bond dissociation energies for the given diatomic iodine species (\(I_2, I_2^+, I_2^-\)). Select the correct option from the list above based on your understanding of the bond formation and dissociation energy principles. ---
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Representations of Organic Compounds
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY