Consider the following reaction occurring at 25C Nitrogen monoxide gas reacts with hydrogen gas to form ammonia gas and water vapor (steam) Use Appendix 2 to obtain-the data required to find the following: (fill in the blanks with a numerical response only. Do not write the units in your answer.) 1. Enthalpy of reaction: AH kJ/mol %3D 2. Entropy of system: AS J/mol 3. Entropy of surroundings: AS J/mol %3D surr 4. Entropy of universe: AS univ J/mol

Consider the following reaction occurring at 25C Nitrogen monoxide gas reacts with hydrogen gas to form ammonia gas and water vapor (steam) Use Appendix 2 to obtain-the data required to find the following: (fill in the blanks with a numerical response only. Do not write the units in your answer.) 1. Enthalpy of reaction: AH kJ/mol %3D 2. Entropy of system: AS J/mol 3. Entropy of surroundings: AS J/mol %3D surr 4. Entropy of universe: AS univ J/mol

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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MISSED THIS? Watch IWE: Standard Enthalpies of Formation; Read Section 7.9. You can click on the Review link to access the section in your eText. Consider the table of Standard Thermodynamic Quantities for Selected Substances at 25 °C. Substance AH; (kJ/mol) Substance AH; (kJ/mol) Substance AH; (kJ/mol) Al(g) HCl(aq) NF₂ (g) Al₂O₂ (s) Cr(g) NH:(E) F(g) C(g) CH₂(g) C₂H₂(g) C₂H₂(g) C₂H6(g) CO(g) CO₂ (g) Cl(g) HCl(g) 330.0 -1675.7 716.7 -74.6 227.4 52.4 -84.68 -110.5 -393.5 121.3 -92.3 HF(g) HF (aq) H(g) Fe(g) FeO(s) Fe₂O₂ (s) Fe₂O4(s) N(g) -167.2 396.6 79.38 -273.3 -335.0 218.0 416.3 -272.0 -824.2 -1118.4 472.7 NH3(aq) O(g) O₂(g) S(g) SO₂(g) SO3(g) Sn(g) SnO(s) SnO₂ (s) -132.1 -45.9 -80.29 249.2 142.7 277.2 -296.8 -395.7 301.2 -280.7 -577.6 Part A Enter an equation for the formation of HF(g) from its elements in their standard states. Express your answer as a chemical equation including phases. Part C ΑΣΦ 6 A chemical reaction does not occur for this question. Part B Complete previous…
Determine the universe entropy change ΔS° (universe) in J/K (with 4 significant figures) for the reaction below at 298.15 K. Note that the temperature of surroundings is also 298.15 K. I2(s) + 3Cl2 (g) → 2 ICl3 (s) The standard entropy change and enthalpy change of the reaction (from the system) are given below: ΔS° (reaction) = -450.33 J/K and ΔH° (reaction) = -179.16 kJ
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy A.S. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations This reaction is spontaneous only above 30. °C but proceeds at a slower rate below 199. °C. This reaction is spontaneous only below 19. °C. This reaction is exothermic and proceeds slower at temperatures below 60. °C. conclusions AH is AS is AH is AS is AH is AS is X (pick one) (pick one) (pick one) ✓ (pick one) (pick one) (pick one) Ś
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A C observations This reaction is slower below 18. °C than above. This reaction is spontaneous only above 97. °C. This reaction is always spontaneous, but proceeds faster at temperatures above 72. °C. AH is AS is conclusions AH is AS is AH is AS is ✓ (pick one) positive negative unknown (pick one) (pick one) (pick one) (pick one)
The decomposition of copper (1) oxide to its elements does not occur spontaneously at 375°C (AG = 140.0 kJ): Cu₂0 (s) 2 Cu (s) + 1/2O₂(g). It can be made to occur spontaneously by being coupled to the oxidation of solid carbon to form carbon monoxide gas at this same temperature (AG = -143.8 kJ): C(s) + 1/2O₂(g) → CO (g) What product(s) is/are produced as a result of coupling the two reactions? CO (g) 2 Cu (s) and 1/2 O₂ (g) 2 Cu (s) and CO (g) 2 Cu (s), 1/2 O2 (g), and CO (g) 1/2 0₂ (g)
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A The reverse of this reaction is always spontaneous. As is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only below 20. °C. As is (pick one) с This reaction is spontaneous except below 85. °C but proceeds at a slower rate below ΔΗ is (pick one) 129. °C. As is (pick one) ×
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations Crystallization of a pure compound is spontaneous only below 23. °C. This reaction is spontaneous only above 31. °C but proceeds at a faster rate above 83. °C. The reverse of this reaction is always spontaneous but proceeds faster at temperatures above 108. °C. AH is AS is AH is AS is conclusions ΔΗ is AS is (pick one) (pick one) (pick one) (pick one) (pick one) (pick one) V
Consider the following reaction: C(graphite) + 1/2 O2 (g) → CO(g) Is it spontaneous under standard conditions at 298 K? Answer this question by calculating AS" (system), AS° (surroundings), and AS (universe). (Define reactants and products as the system.) S* (J/mol · K) A¡H° (kJ/mol) at 298 K (kJ/mol) Compound at 298 K C(s, graphite) 5.6 CO(g) 197.674 -110.525 CS2 (g) 237.8 116.7 CCL (e) 214.39 -128.4 Cl2 (g) 223.08 Si(s) 18.82 SİCL, (g) 330.86 -662.75 S(s, rhombic) 32.1 Br2 (e) 152.2 HBr(g) 198.70 -36.29 H2 (g) 130.7 H2O2 (e) 109.6 -187.78 O2 (g) 205.07 O yes O no
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy ▴ and reaction entropy as. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B C observations The reverse of this reaction is always spontaneous. This reaction is spontaneous except above 64. °C. This reaction is always spontaneous, but proceeds faster at temperatures below 77. °C. AH is AS is conclusions AH is AS is AH is AS is x (pick one) (pick one) (pick one) (pick one) (pick one) (pick one)
Calculate AGran in kJ, at 298K for the following reaction using the conditions given below. R = 8.314 J/mol.K SO3 (g) + H₂O (9) H₂SO4 (1) AGran = -90.5 (A) mol Pso3 = 0.20 atm, Pu,o = 0.88 atm Express your answer to one decimal place.
Consider the reaction. 2CO₂(g) +5H₂(g) C₂H₂(g) + 4H₂O(g) Using the standard thermodynamic data in the tables linked above, calculate AG for this reaction at 298.15K if the pressure of each gas is 13.84 mm Hg. ANSWER: kJ/mol
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entre AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions This reaction is always spontaneous, but proceeds faster at temperatures below AH is (pick one) 132. °C. AS is (pick one) v AH is (pick one) ♥ This reaction is spontaneous except below 3. °C. B AS is (pick one) ♥ ΔΗ is (pick one) ♥ This reaction is spontaneous only below 44. °C. AS is (pick one) ♥