Consider the following reaction between Diene A with one equivalent of D-Br, noting deuterium (an isotope of hydrogen) is present rather than hydrogen in the acid. Use the diene numbering scheme provided as you draw your products. 3. + D-Br 2 Diene A 1,2-product 1,4-product a. (8) Draw the major products of this reaction in the spaces provided above. b. (2) Circle the kinetic product. c. (2) Underline the thermodynamic product. d. (2) T or F. The thermodynamic product is less stable than the kinetic product. e. (2) T or F. The kinetic product is formed more slowly than the thermodynamic product. f. (2) T or F. Low reaction temperatures favor the thermodynamic product. Draw the mechanism for the formation of the 1,4-product you drew in 3.a. above, ensuring you include all electron pairs, electron-pushing arrows and intermediates.
Consider the following reaction between Diene A with one equivalent of D-Br, noting deuterium (an isotope of hydrogen) is present rather than hydrogen in the acid. Use the diene numbering scheme provided as you draw your products. 3. + D-Br 2 Diene A 1,2-product 1,4-product a. (8) Draw the major products of this reaction in the spaces provided above. b. (2) Circle the kinetic product. c. (2) Underline the thermodynamic product. d. (2) T or F. The thermodynamic product is less stable than the kinetic product. e. (2) T or F. The kinetic product is formed more slowly than the thermodynamic product. f. (2) T or F. Low reaction temperatures favor the thermodynamic product. Draw the mechanism for the formation of the 1,4-product you drew in 3.a. above, ensuring you include all electron pairs, electron-pushing arrows and intermediates.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Consider the following reaction between Diene A with one equivalent of D-Br, noting deuterium (an
isotope of hydrogen) is present rather than hydrogen in the acid. Use the diene numbering scheme
provided as you draw your products.
3.
+ D-Br
2
Diene A
1,2-product
1,4-product
a. (8) Draw the major products of this reaction in the spaces provided above.
b. (2) Circle the kinetic product.
c. (2) Underline the thermodynamic product.
d. (2) T or F. The thermodynamic product is less stable than the kinetic product.
e. (2) T or F. The kinetic product is formed more slowly than the thermodynamic product.
f. (2) T or F. Low reaction temperatures favor the thermodynamic product.
Draw the mechanism for the formation of the 1,4-product you drew in 3.a. above, ensuring you
include all electron pairs, electron-pushing arrows and intermediates.
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