Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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hello i am having trouble doing this steady state approximation question. I posted the images of the question. can you please show me how you got the answer for each one for more understanding. That will be appreciated.
![Consider the following generic two-step reaction mechanism.
k₁
Step 1:
A + B
Step 2: A + C
k₂
k3
-
C + D
B + D](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F3f3c205e-0837-421d-a515-2f3294f1847e%2F89d018fb-e136-4d4e-93c5-780859018de4%2Fckmtrbk_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Consider the following generic two-step reaction mechanism.
k₁
Step 1:
A + B
Step 2: A + C
k₂
k3
-
C + D
B + D
![Match the expressions to complete the equations, making use of the Steady State Approximation.
k₁ [A][B]
A k2k3[A][D]
2k1k3[A]²[B]
k2[D]
c 2k₁ [A][B]
B
D
k₁[A][B]
k3 [A]
E k₁[A][B]-k₂[C][D]-k3[A][C]
k₁[A] [B]
F k2[D]+k3[A]
2k1k3[A]²[B]
k2[D]+k3[A]
H None of the above
G
Ev
F v
B V
Dv
=[C]
d[C]
dt
||
22
22
d[D]
dt
(when k3 << k₁ ~ k ₂)
(in all instances)
(when k3 >> k₁ ~k ₂)
d[A]
dt
dt](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F3f3c205e-0837-421d-a515-2f3294f1847e%2F89d018fb-e136-4d4e-93c5-780859018de4%2Ftgdd6fg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Match the expressions to complete the equations, making use of the Steady State Approximation.
k₁ [A][B]
A k2k3[A][D]
2k1k3[A]²[B]
k2[D]
c 2k₁ [A][B]
B
D
k₁[A][B]
k3 [A]
E k₁[A][B]-k₂[C][D]-k3[A][C]
k₁[A] [B]
F k2[D]+k3[A]
2k1k3[A]²[B]
k2[D]+k3[A]
H None of the above
G
Ev
F v
B V
Dv
=[C]
d[C]
dt
||
22
22
d[D]
dt
(when k3 << k₁ ~ k ₂)
(in all instances)
(when k3 >> k₁ ~k ₂)
d[A]
dt
dt
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