Consider the following for the mechanism oxidation of bromide ions by hydrogen peroxide in aqueous acid solution. Elementary Step 1 H+ + H₂O₂ = {H₂O*- 2 OH) (rapid equilibrium) Elementary Step 2 (H₂O+-OH) + Br¯ → HOBr + H₂O (slowest) Elementary Step 3 HOBr + H+ + Br¯ → Br₂ + H₂O (fast) Consider the reaction profile below. Approximate the AH for the overall reaction.
Consider the following for the mechanism oxidation of bromide ions by hydrogen peroxide in aqueous acid solution. Elementary Step 1 H+ + H₂O₂ = {H₂O*- 2 OH) (rapid equilibrium) Elementary Step 2 (H₂O+-OH) + Br¯ → HOBr + H₂O (slowest) Elementary Step 3 HOBr + H+ + Br¯ → Br₂ + H₂O (fast) Consider the reaction profile below. Approximate the AH for the overall reaction.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Consider the following
mechanism
for the
oxidation of bromide
ions by hydrogen
peroxide in aqueous
acid solution.
Elementary Step 1
H+ + H₂O₂ = {H₂O*-
2
OH) (rapid
equilibrium)
Elementary Step 2
(H₂O-OH) + Br¯ →
HOBr + H₂O (slowest)
Elementary Step 3
HOBr + H+ + Br¯ → Br₂ +
H₂O (fast)
Consider the reaction
profile below.
Approximate the AH for
the overall reaction.

Transcribed Image Text:Potential Energy (kJ/mol)
Reacton Profile
360
280
160
140
100
60
O
Reaction Progress
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