Consider the following elementary reaction (seen in air pollution) that goes through a a theoretically proposed transition state: NO2 (9) + NO2 (9) > (0ON – NOO) - > N3O4 (9)

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Chapter1: Chemical Foundations
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Consider the following elementary reaction (seen in air pollution) that goes through a a theoretically
proposed transition state:
NO2 (9) + NO2 (9) – > (0ON – NOO)* – > N204 (9)
Molecule
Energy in kJ/mol
Entropy in J/(mol*K)
NO2
-535913
240
(OON-NOO);
-535854
400
N204
-107439
304
Use collision theory to estimate the second order rate constant at 25 °C using that
the hard sphere molecular cross section is 0.60 nm².
Transcribed Image Text:Consider the following elementary reaction (seen in air pollution) that goes through a a theoretically proposed transition state: NO2 (9) + NO2 (9) – > (0ON – NOO)* – > N204 (9) Molecule Energy in kJ/mol Entropy in J/(mol*K) NO2 -535913 240 (OON-NOO); -535854 400 N204 -107439 304 Use collision theory to estimate the second order rate constant at 25 °C using that the hard sphere molecular cross section is 0.60 nm².
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