You have studied the gas-phase oxidation of HBr by O2:4 HBr(g) + O2(g) -->2 H2O(g) + 2 Br2(g) You find the reaction to be first order with respect to HBrand first order with respect to O2. You propose the followingmechanism:HBr(g) + O2(g) ---> HOOBr(g) HOOBr(g) + HBr(g) --->2 HOBr(g) HOBr(g) + HBr(g) ----> H2O(g) + Br2(g) (a) Confirm that the elementary reactions add to give theoverall reaction. (b) Based on the experimentally determinedrate law, which step is rate determining? (c) Whatare the intermediates in this mechanism? (d) If you areunable to detect HOBr or HOOBr among the products,does this disprove your mechanism?

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Chapter1: Chemical Foundations
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You have studied the gas-phase oxidation of HBr by O2:
4 HBr(g) + O2(g) -->2 H2O(g) + 2 Br2(g)
You find the reaction to be first order with respect to HBr
and first order with respect to O2. You propose the following
mechanism:
HBr(g) + O2(g) ---> HOOBr(g)
HOOBr(g) + HBr(g) --->2 HOBr(g)
HOBr(g) + HBr(g) ----> H2O(g) + Br2(g)
(a) Confirm that the elementary reactions add to give the
overall reaction. (b) Based on the experimentally determined
rate law, which step is rate determining? (c) What
are the intermediates in this mechanism? (d) If you are
unable to detect HOBr or HOOBr among the products,
does this disprove your mechanism?

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