Consider the equilibrium system described by the chemical reaction below. For this reaction, Kp = 4.51 x 10- at a particular temperature. Calculate the value of Qp for the initial set reaction conditions: 57 atm NH3, 27 atm N2, 82 atm H2. N2(g) + 3 H2(g)=2 NH3(g) 1 Based on the given data, set up the expression for Qp and then evaluate it. Do not

Consider the equilibrium system described by the chemical reaction below. For this reaction, Kp = 4.51 x 10- at a particular temperature. Calculate the value of Qp for the initial set reaction conditions: 57 atm NH3, 27 atm N2, 82 atm H2. N2(g) + 3 H2(g)=2 NH3(g) 1 Based on the given data, set up the expression for Qp and then evaluate it. Do not

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Nitrogen monoxide and water react to form ammonia and oxygen, like this: 4NO(g)+6H2O(g)——> 4NH3(g)+ 5O2(g) Also, a chemist finds that at a certain temperature the equilibrium mixture of nitrogen monoxide, water, ammonia, and oxygen has the following composition(picture). Calculate the value of the equilibrium constant Kp for this reaction. Round your answer to 2 significant digits.
A chemical engineer is studying the following reaction: N₂(g) + 3H₂(g) → 2 NH3(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.018. The engineer charges ("fills") three reaction vessels with nitrogen and hydrogen, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel compound pressure expected change in pressure N₂ 11.46 atm ↑ increase ↓decrease (no change) H, 18.35 atm A ↑ increase ↓ decrease (no change) NH3 32.54 atm ↑ increase (no change) N₂ 10.77 atm ↑ increase ↓ decrease ↓decrease ↓decrease decrease B H₂ 16.30 atm (no change) (no change) (no change) ↑ increase 33.91 atm ↑ increase NH3 N₂₂ 11.20 atm ↑ increase ↓ decrease (no change) H₂ 17.58 atm с ↑ increase ↓decrease (no change) NH₂ 33.05 atm ↑…
Nitrogen monoxide and ozone react to form nitrogen dioxide and oxygen, like this: NO(g) + O₂(g) → NO₂(g) + O₂(g) The reaction is exothermic. Suppose a mixture of NO, O3, NO₂ and O₂ has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition The temperature is raised. The pressure of O3 will The temperature is lowered. ? The pressure of NO₂ will ? shift in equilibrium O to the right to the left O (none) O to the right to the left O (none) X
Consider the equilibrium system described by the chemical reaction below. If the partial pressures at equilibrium of NO, Cl2, and NOCI are 0.095 atm, 0.171 atm, and 0.28 atm, respectively, in a reaction vessel of 7.00 L at 500 K, what is the value of Kp for this reaction? 2 NO(g) + Cl2(g) = 2 NOCI(g)
Consider the reaction: 2 H2S (g) ⇋ 2 H2 (g) + S2 (g) Kp = 2.4 x 10 -4 at 1073 K If the initial pressure of hydrogen sulfide is 755 torr, what will be the equilibrium partial pressure of each gas?
A chemical engineer is studying the following reaction: N₂(g) + 3H₂(g) → 2 NH3(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.018. The engineer charges ("fills") three reaction vessels with nitrogen and hydrogen, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel compound pressure expected change in pressure N₂ 11.46 atm ↑ increase ↓ decrease (no change) A H₂ 18.35 atm ↑ increase ↓ decrease (no change) NH3 32.54 atm ↑ increase ↓decrease (no change) N2₂ 10.77 atm ↑ increase B H₂ 16.30 atm ↑ increase ↓decrease decrease ↓decrease (no change) (no change) (no change) (no change) NH₂ 33.91 atm O ↑ increase N₂ 11.20 atm ↑ increase C H₂ 17.58 atm O ↑ increase ↓ decrease ↓decrease ↓decrease (no change) NH3…
Methane and water react to form hydrogen and carbon monoxide, like this: CH4(g) + H₂O(g) → 3 H₂(g) + CO(g) The reaction is endothermic. Suppose a mixture of CH4, H₂O, H₂ and CO has come to equilibrium in a closed reaction vessel. Predict what change, if perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. any, the perturbation change in composition The temperature is raised. The pressure of CH4 will The temperature is lowered. The pressure of H₂ will ? ? ↑ î shift in equilibrium O X to the right to the left (none) to the right to the left (none) Ś
A chemical engineer is studying the following reaction: H2(9)+Cl2(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.1. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel compound pressure expected change in pressure H, 2.75 atm t increase I decrease (no change) Cl, 4.00 atm t increase O I decrease O (no change) A HCI 2.10 atm O f increase OI decrease O (no change) H, 2.78 atm t increase I decrease O (no change) Cl, 4.03 atm t increase I decrease (no change) 2.06 atm t increase I decrease (no change) HCl H2 3.22 atm O f increase I decrease (no change) t increase I decrease (no change) Cl, 4.98 atm OI decrease O (no change) H CI 4.26 atm…
3. Consider the reaction Br2 (g) + Cl2 (g) 2 BrCl (g) Kp = 1.11 x 104 at 150 K. A reaction mixture initially contains a Br2 partial pressure of 0.993 atm and a Cl2 partial pressure of 0.967 atm at 150 K. Calculate the equilibrium partial pressure of each reactant and product. 4. Consider the reaction CO₂ (g) + H2 (g) A reaction mixture initially contains a CO partial pressure of 1.768 atm and a H₂O partial pressure of 2.324 atm at 2000 K. Calculate the equilibrium partial pressures of each reactant and product. CO (g) + H₂O (g) Kp = 0.0611 at 2000K.
A chemical engineer is studying the following reaction: BF3(aq) + NH3(aq) → BF3NH₂(aq) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.9. с The engineer charges ("fills") three reaction vessels with boron trifluoride and ammonia, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A B с compound BF 3 NH3 BF₂NH₂ BE 3 NH3 BF, NH3 BF3 NH3 BF3NH₂ concentration 0.65 M 0.70 M 0.88 M 0.03 M 0.07 M 1.06 M 0.04 M 0.08 M 1.05 M expected change in concentration ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↓ decrease ↓ decrease ↓ decrease ↓ decrease ↓ decrease ↓ decrease ↓ decrease decrease ↓ decrease X (no change) (no change) (no change) (no change) (no change)…
For the reaction 2 A(g) = B(g) + 3 C(g), we begin with only pure A(g) and the total pressure is 8.00 atm. We attain equilibrium. At equilibrium, the total pressure is 12.00 atm. What is the value of ∆G◦ for this reaction? The temperature is 25.0 ◦C throughout.
Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 500. mL flask with 3.3 atm of sulfur dioxide gas and 3.2 atm of oxygen gas, and when the mixture has come to equilibrium measures the partial pressure of sulfur trioxide gas to be 2.6 atm. Calculate the pressure equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits. K₁ = 0 P x10 X Ś