Consider a saturated solution of AgBr in 0.010 M NH3. AgBr (s) Ag* + NH3 (aq) Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2* Kr = 8.13 x103 NH3 (aq) + H2O 5 NH4* + OH- = 5.0 x10-13 2.04 x103 S Ag* + Br Ksp S Ag(NH3)* Kr %3D Kb = 1.75 x10-5 H2O $ H* + OH- Kw = 1.00 x10-14 a. How many unknown concentrations must be solved? How many equations are required? b. Write a charge balance equation for the system. Write a mass balance equation for the system.

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Consider a saturated solution of AgBr in 0.010 M NH3.
AgBr (s) 5 Ag* + Br
Ag* + NH3 (aq)
Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2*
Ksp = 5.0 x10-13
Kr = 2.04 x103
5 Ag(NH3)*
Kr = 8.13 x103
NH3 (aq) + H2O 5 NH4* + OH¯
1.75 x105
H2O S H* + OH-
Kw = 1.00 x10-14
a. How many unknown concentrations must be solved? How many equations are required?
b. Write a charge balance equation for the system.
c. Write a mass balance equation for the system.
Transcribed Image Text:Consider a saturated solution of AgBr in 0.010 M NH3. AgBr (s) 5 Ag* + Br Ag* + NH3 (aq) Ag(NH3)* + NH3 (aq) 5 Ag(NH3)2* Ksp = 5.0 x10-13 Kr = 2.04 x103 5 Ag(NH3)* Kr = 8.13 x103 NH3 (aq) + H2O 5 NH4* + OH¯ 1.75 x105 H2O S H* + OH- Kw = 1.00 x10-14 a. How many unknown concentrations must be solved? How many equations are required? b. Write a charge balance equation for the system. c. Write a mass balance equation for the system.
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