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Consider a closed vessel initially containing 1 mol of pure ethyl acetate at 70°C and 86 kPa. Imagine that pure ethanol is slowly added at constant temperature and pressure until the vessel contains 1 mol ethyl acetate and 9 mol ethanol. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such process. What sort of device would be required? How would the total system volume change during this process? At what composition would the system volume reach its maximum volume?

Consider a closed vessel initially containing 1 mol of pure ethyl acetate at 70°C and 86 kPa. Imagine that pure ethanol is slowly added at constant temperature and pressure until the vessel contains 1 mol ethyl acetate and 9 mol ethanol. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such process. What sort of device would be required? How would the total system volume change during this process? At what composition would the system volume reach its maximum volume?

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Consider a closed vessel initially containing 1 mol of pure ethyl acetate at 70°C and 86 kPa. Imagine that pure ethanol is slowly added at constant temperature and pressure until the vessel contains 1 mol ethyl acetate and 9 mol ethanol. Describe the evolution of phases and phase compositions during this process. Comment on the practical feasibility of carrying out such process. What sort of device would be required? How would the total system volume change during this process? At what composition would the system volume reach its maximum volume?

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