Consider 2 mole of argon gas at 500K compacted in 6 L of total volume of 11 L. The heat capacity at constant volume, Cv = 12.48 JK-1mol-1. Use the data from the Appendix to help you answer the following questions. Consider isothermal irreversible expansion against a constant external pressure of 1 atmosphere. Calculate: ΔSs = ΔSR = ΔSUniv = Consider isothermal reversible expansion against a constant external pressure of 1 atmosphere. Calculate; ΔSs = ΔSR = ΔSUniv = Consider adiabatic irreversible expansion against a constant external pressure of 1 atmosphere. Calculate: W = ΔSs = ΔT = ΔSs = ΔSR = ΔSuniv = Consider adiabatic reversible expansion against a constant external pressure of 1 atmosphere. Calculate: W = ΔSs = ΔT = ΔSs = ΔSR = ΔSuniv = Consider 2 mole of argon gas at 500K compacted in 6 L of total volume of 11 L. The heat capacity at constant volume, Cv = 12.48 JK-1mol-1. Use the data from the Appendix to help you answer the following questions. Consider isothermal irreversible expansion against a constant external pressure of 1 atmosphere. Calculate: ΔSs = ΔSR = ΔSUniv = Consider isothermal reversible expansion against a constant external pressure of 1 atmosphere. Calculate; ΔSs = ΔSR = ΔSUniv = Consider adiabatic irreversible expansion against a constant external pressure of 1 atmosphere. Calculate: W = ΔSs = ΔT = ΔSs = ΔSR = ΔSuniv = Consider adiabatic reversible expansion against a constant external pressure of 1 atmosphere. Calculate: W = ΔSs = ΔT = ΔSs = ΔSR = ΔSuniv =

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter2: The First Law Of Thermodynamics
Section: Chapter Questions
Problem 2.92E
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  1. Consider 2 mole of argon gas at 500K compacted in 6 L of total volume of 11 L. The heat capacity at constant volume, Cv = 12.48 JK-1mol-1. Use the data from the Appendix to help you answer the following questions.
  2. Consider isothermal irreversible expansion against a constant external pressure of 1 atmosphere. Calculate:
  • ΔSs =
  • ΔSR =
  • ΔSUniv =
  1. Consider isothermal reversible expansion against a constant external pressure of 1 atmosphere. Calculate;
  • ΔSs =
  • ΔSR =
  • ΔSUniv =
  1. Consider adiabatic irreversible expansion against a constant external pressure of 1 atmosphere. Calculate:
  • W =
  • ΔSs =
  • ΔT =
  • ΔSs =
  • ΔSR =
  • ΔSuniv =
  1. Consider adiabatic reversible expansion against a constant external pressure of 1 atmosphere. Calculate:
  • W =
  • ΔSs =
  • ΔT =
  • ΔSs =
  • ΔSR =
  • ΔSuniv =
    1. Consider 2 mole of argon gas at 500K compacted in 6 L of total volume of 11 L. The heat capacity at constant volume, Cv = 12.48 JK-1mol-1. Use the data from the Appendix to help you answer the following questions.
    2. Consider isothermal irreversible expansion against a constant external pressure of 1 atmosphere. Calculate:
    • ΔSs =
    • ΔSR =
    • ΔSUniv =
    1. Consider isothermal reversible expansion against a constant external pressure of 1 atmosphere. Calculate;
    • ΔSs =
    • ΔSR =
    • ΔSUniv =
    1. Consider adiabatic irreversible expansion against a constant external pressure of 1 atmosphere. Calculate:
    • W =
    • ΔSs =
    • ΔT =
    • ΔSs =
    • ΔSR =
    • ΔSuniv =
    1. Consider adiabatic reversible expansion against a constant external pressure of 1 atmosphere. Calculate:
    • W =
    • ΔSs =
    • ΔT =
    • ΔSs =
    • ΔSR =
    • ΔSuniv =
Irreversible Expansion
against constant pressure
Isothermal
Adiabatic
Reversible expansion
or compression
Isothermal
Adiabatic
W
-PAV
-PAV
CAT
#
q
-ARTIN NATIN
#1 3
PerAV
ex
0
0
V₁
AU
0
0
-PAV AU + A(PV)
CAT
ΔΗ
"Sec Steb
0
0
AU + A(PV)
AT
-PAV
C₂
Q).
T₁[(V/V₂)-1]
cl
AS
nRin
nRin
0
="/
V₁
dT+nRin
ds = cu di
T
ind
1. AK
toute
Ak
APPENDIX H
Transcribed Image Text:Irreversible Expansion against constant pressure Isothermal Adiabatic Reversible expansion or compression Isothermal Adiabatic W -PAV -PAV CAT # q -ARTIN NATIN #1 3 PerAV ex 0 0 V₁ AU 0 0 -PAV AU + A(PV) CAT ΔΗ "Sec Steb 0 0 AU + A(PV) AT -PAV C₂ Q). T₁[(V/V₂)-1] cl AS nRin nRin 0 ="/ V₁ dT+nRin ds = cu di T ind 1. AK toute Ak APPENDIX H
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,