Homework Help is Here – Start Your Trial Now!
Science
Chemistry
CONCEPT QUESTIONS Predict the Product. Provide the stable organic product(s) for the reactions below 1. 1 eq -NH₂ Å 2. H₂O/ HCI HO CI OH 1. (excess) X NH₂ 2. H₂O NH₂ 1.1 eq -NH₂ å & 2. H₂O/HCI pyridine

CONCEPT QUESTIONS Predict the Product. Provide the stable organic product(s) for the reactions below 1. 1 eq -NH₂ Å 2. H₂O/ HCI HO CI OH 1. (excess) X NH₂ 2. H₂O NH₂ 1.1 eq -NH₂ å & 2. H₂O/HCI pyridine

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

2a and 2b

**Concept Questions** **Predict the Product.** Provide the stable organic product(s) for the reactions below. 1. The top reaction: - **Reactants:** - Left: Cyclohexane-1,3-dione with a methyl group at one of the dione carbons. - Right: Propylamine (1 equivalent). - **Steps:** - 1. 1 eq. Propylamine (NH₂) - 2. H₂O / HCl 2. The second reaction: - **Reactants:** - Left: Acetyl chloride (ethanoyl chloride). - Right: Tetrahydrofuran-2-ol. - **Steps:** - 1. Pyridine 3. The third reaction: - **Reactants:** - Left: 2-aminophenol. - Right: Diketene (excess). - **Steps:** - 1. Diketene (excess) - 2. H₂O 4. The bottom reaction: - **Reactants:** - Left: 1,3-benzodioxole-4,5-dione. - Right: Piperazine (1 equivalent). - **Steps:** - 1. 1 eq. Piperazine (NH₂) - 2. H₂O / HCl --- In each of the above reactions, the stable organic products formed will depend on the interaction between the reagents and their functional groups, along with the reaction conditions specified. - The first reaction typically results in the formation of an imine due to the reaction of a ketone and amine, followed by hydrolysis in acidic conditions. - The second reaction is an esterification reaction facilitated by pyridine which may result in the formation of an ester. - The third reaction involves the formation of a lactam when diketene reacts with 2-aminophenol and water hydrolyzes it. - The fourth reaction may produce a hydroxamic acid through reaction with piperazine followed by hydrolysis. Detailed mechanisms and exact product structures would require drawing tools and a step-by-step mechanistic description.
Transcribed Image Text:**Concept Questions** **Predict the Product.** Provide the stable organic product(s) for the reactions below. 1. The top reaction: - **Reactants:** - Left: Cyclohexane-1,3-dione with a methyl group at one of the dione carbons. - Right: Propylamine (1 equivalent). - **Steps:** - 1. 1 eq. Propylamine (NH₂) - 2. H₂O / HCl 2. The second reaction: - **Reactants:** - Left: Acetyl chloride (ethanoyl chloride). - Right: Tetrahydrofuran-2-ol. - **Steps:** - 1. Pyridine 3. The third reaction: - **Reactants:** - Left: 2-aminophenol. - Right: Diketene (excess). - **Steps:** - 1. Diketene (excess) - 2. H₂O 4. The bottom reaction: - **Reactants:** - Left: 1,3-benzodioxole-4,5-dione. - Right: Piperazine (1 equivalent). - **Steps:** - 1. 1 eq. Piperazine (NH₂) - 2. H₂O / HCl --- In each of the above reactions, the stable organic products formed will depend on the interaction between the reagents and their functional groups, along with the reaction conditions specified. - The first reaction typically results in the formation of an imine due to the reaction of a ketone and amine, followed by hydrolysis in acidic conditions. - The second reaction is an esterification reaction facilitated by pyridine which may result in the formation of an ester. - The third reaction involves the formation of a lactam when diketene reacts with 2-aminophenol and water hydrolyzes it. - The fourth reaction may produce a hydroxamic acid through reaction with piperazine followed by hydrolysis. Detailed mechanisms and exact product structures would require drawing tools and a step-by-step mechanistic description.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Gravimetric Analysis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS