Compressing a sample of ideal gas irreversibly requires 1.8 kJ of work to be done on the sample of gas by the surroundings. a) Explain the sign of work. Provide an explanation to support your answer that includes what is occurring in the gas sample on the molecular level. b) Would the work when compressing the gas reversibly be less than or greater than the irreversible work given above? Explain your choice
Compressing a sample of ideal gas irreversibly requires 1.8 kJ of work to be done on the sample of gas by the surroundings. a) Explain the sign of work. Provide an explanation to support your answer that includes what is occurring in the gas sample on the molecular level. b) Would the work when compressing the gas reversibly be less than or greater than the irreversible work given above? Explain your choice
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Compressing a sample of ideal gas irreversibly requires 1.8 kJ of work to be done on the sample of gas by the surroundings.
a) Explain the sign of work. Provide an explanation to support your answer that includes what is occurring in the gas sample on the molecular level.
b) Would the work when compressing the gas reversibly be less than or greater than the irreversible work given above? Explain your choice.
Expert Solution

Step 1
a) By convention, when work is done on the gas (system) by the surroundings, the work is positive.
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