Complete the half-reactions for the cell shown, and show the shorthand notation for the cell. The electrode on the left is anode, and the one on the right is the cathode. Anode half-reaction: + 2 Cl¯ 2 + 2 e- Cathode half-reaction: + 2 e- 2 + 2 Cl- Shorthand notation: Answer Bank Ag(s) Pb(s) PBCI,(s) 2 Ag(s) 2 AgCI(s) CI"(aq) AgCl(s) V

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Galvanic Cell Diagram Description**

This diagram illustrates a galvanic cell setup composed of two half-cells. 

- **Left Half-Cell (Lead Half-Cell):**
  - Contains a lead (Pb) electrode.
  - The electrolyte solution is potassium chloride (KCl) aqueous solution.
  - A solid lead(II) chloride (PbCl₂) precipitate is in contact with the lead electrode, indicating a reaction involving lead ions.

- **Right Half-Cell (Silver Half-Cell):**
  - Contains a silver (Ag) electrode.
  - The electrolyte solution is also potassium chloride (KCl) aqueous solution.
  - Solid silver chloride (AgCl) is present, indicating a reaction involving silver ions.

- **Salt Bridge:**
  - A U-shaped tube filled with electrolyte (often KCl) connects the two beakers, allowing the transfer of ions to maintain electrical neutrality.

- **External Circuit:**
  - The setup includes an external wire connecting the Pb and Ag electrodes. A voltmeter is placed in the circuit to measure the potential difference between the electrodes.
  - The flow of electrons is from the lead electrode to the silver electrode through the external circuit.

This setup demonstrates a typical galvanic cell, showing the electrochemical processes that occur between two metal electrodes in different electrolyte solutions, driven by their chemical reactions.
Transcribed Image Text:**Galvanic Cell Diagram Description** This diagram illustrates a galvanic cell setup composed of two half-cells. - **Left Half-Cell (Lead Half-Cell):** - Contains a lead (Pb) electrode. - The electrolyte solution is potassium chloride (KCl) aqueous solution. - A solid lead(II) chloride (PbCl₂) precipitate is in contact with the lead electrode, indicating a reaction involving lead ions. - **Right Half-Cell (Silver Half-Cell):** - Contains a silver (Ag) electrode. - The electrolyte solution is also potassium chloride (KCl) aqueous solution. - Solid silver chloride (AgCl) is present, indicating a reaction involving silver ions. - **Salt Bridge:** - A U-shaped tube filled with electrolyte (often KCl) connects the two beakers, allowing the transfer of ions to maintain electrical neutrality. - **External Circuit:** - The setup includes an external wire connecting the Pb and Ag electrodes. A voltmeter is placed in the circuit to measure the potential difference between the electrodes. - The flow of electrons is from the lead electrode to the silver electrode through the external circuit. This setup demonstrates a typical galvanic cell, showing the electrochemical processes that occur between two metal electrodes in different electrolyte solutions, driven by their chemical reactions.
### Electrochemical Cell Reactions

Complete the half-reactions for the cell shown, and provide the shorthand notation for the cell. The electrode on the left is the anode, while the electrode on the right is the cathode.

#### Anode Half-Reaction:
\[ \underline{\phantom{Ag(s)}} + 2 \text{Cl}^- \rightleftharpoons \underline{\phantom{AgCl(s)}} + 2e^- \]

#### Cathode Half-Reaction:
\[ \underline{\phantom{PbCl_2(s)}} + 2e^- \rightleftharpoons \underline{\phantom{Pb(s)}} + 2 \text{Cl}^- \]

#### Shorthand Notation:
\[ \underline{\phantom{}} \,|\, \underline{\phantom{}} \,||\, \underline{\phantom{}} \,|\, \underline{\phantom{}} \]

#### Answer Bank:
- Ag(s)
- Pb(s)
- PbCl₂(s)
- 2 Ag(s)
- 2 AgCl(s)
- Cl⁻(aq)
- AgCl(s)

### Explanation:

- **Anode:** In electrochemical cells, the anode is where oxidation occurs. In this half-cell reaction, a solid reacts with chloride ions to form a solid compound and release electrons.
- **Cathode:** The cathode is where reduction occurs. A compound gains electrons, releasing chloride ions, and forms a solid metal.
- **Shorthand Notation:** This notation summarizes the entire cell reaction, separating the anode and cathode components by a double vertical line, indicating the salt bridge or membrane.

### Diagram Explanation:

The bottom image depicts a voltmeter connected to the electrodes, indicating that a current is flowing, which is typical for galvanic cells generating electrical energy through spontaneous redox reactions.
Transcribed Image Text:### Electrochemical Cell Reactions Complete the half-reactions for the cell shown, and provide the shorthand notation for the cell. The electrode on the left is the anode, while the electrode on the right is the cathode. #### Anode Half-Reaction: \[ \underline{\phantom{Ag(s)}} + 2 \text{Cl}^- \rightleftharpoons \underline{\phantom{AgCl(s)}} + 2e^- \] #### Cathode Half-Reaction: \[ \underline{\phantom{PbCl_2(s)}} + 2e^- \rightleftharpoons \underline{\phantom{Pb(s)}} + 2 \text{Cl}^- \] #### Shorthand Notation: \[ \underline{\phantom{}} \,|\, \underline{\phantom{}} \,||\, \underline{\phantom{}} \,|\, \underline{\phantom{}} \] #### Answer Bank: - Ag(s) - Pb(s) - PbCl₂(s) - 2 Ag(s) - 2 AgCl(s) - Cl⁻(aq) - AgCl(s) ### Explanation: - **Anode:** In electrochemical cells, the anode is where oxidation occurs. In this half-cell reaction, a solid reacts with chloride ions to form a solid compound and release electrons. - **Cathode:** The cathode is where reduction occurs. A compound gains electrons, releasing chloride ions, and forms a solid metal. - **Shorthand Notation:** This notation summarizes the entire cell reaction, separating the anode and cathode components by a double vertical line, indicating the salt bridge or membrane. ### Diagram Explanation: The bottom image depicts a voltmeter connected to the electrodes, indicating that a current is flowing, which is typical for galvanic cells generating electrical energy through spontaneous redox reactions.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Electrochemical Cells
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY