**Complete the following reaction scheme. Give all product(s) and indicate major or minor and any relevant stereochemistry.****(g)**- Structure: Cyclohexene- Reagents: 1) BH₃, THF 2) H₂O₂, OH⁻**(h)**- Structure: 1-Methylcyclohexene- Reagents: 1) Hg(OAc)₂, H₂O 2) NaBH₄**(i)**- Structure: 1,4-Hexadiene- Reagents: - KMnO₄, NaOH, Cold**Explanation of Reactions:**- **(g) Hydroboration-Oxidation of Cyclohexene:** - The reaction involves the addition of borane (BH₃) followed by oxidation. This results in syn-addition, typically leading to the formation of cyclohexanol with anti-Markovnikov selectivity.- **(h) Oxymercuration-Reduction of 1-Methylcyclohexene:** - The oxymercuration step involves the addition of mercuric acetate, followed by reduction with sodium borohydride (NaBH₄), resulting in Markovnikov addition to form 1-methylcyclohexanol.- **(i) Dihydroxylation of 1,4-Hexadiene:** - Cold, dilute alkaline potassium permanganate (KMnO₄) oxidizes the alkene to produce vicinal diols (glycols), yielding two hydroxyl groups added to each double-bonded carbon with syn-stereochemistry.

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Answered: Complete the following reaction scheme.…

Complete the following reaction scheme. Give all product(s) and indicate major or minor and any relevant stereochemistry (g) 1) BH 3, THF 2) H202. OH- (h) 1) Hg(OAC),, H0 2) NaBH4 KMNO4, NaOH Cold

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

**Complete the following reaction scheme. Give all product(s) and indicate major or minor and any relevant stereochemistry.**

**(g)**
- Structure: Cyclohexene
- Reagents:
1) BH₃, THF
2) H₂O₂, OH⁻

**(h)**
- Structure: 1-Methylcyclohexene
- Reagents:
1) Hg(OAc)₂, H₂O
2) NaBH₄

**(i)**
- Structure: 1,4-Hexadiene
- Reagents:
- KMnO₄, NaOH, Cold

**Explanation of Reactions:**

- **(g) Hydroboration-Oxidation of Cyclohexene:**
- The reaction involves the addition of borane (BH₃) followed by oxidation. This results in syn-addition, typically leading to the formation of cyclohexanol with anti-Markovnikov selectivity.

- **(h) Oxymercuration-Reduction of 1-Methylcyclohexene:**
- The oxymercuration step involves the addition of mercuric acetate, followed by reduction with sodium borohydride (NaBH₄), resulting in Markovnikov addition to form 1-methylcyclohexanol.

- **(i) Dihydroxylation of 1,4-Hexadiene:**
- Cold, dilute alkaline potassium permanganate (KMnO₄) oxidizes the alkene to produce vicinal diols (glycols), yielding two hydroxyl groups added to each double-bonded carbon with syn-stereochemistry.

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