HO OH 1. DHP, cat. H* 3. (a) KH, THF, 0°℃ (b) PhCH₂Br 2. (a) LiAlH4, THF (b) NaOH, H₂O 4. H*, H₂O 5. Jones Oxidation Ph oplo OH

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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 Complete each of the following reactions by providing missing reagents, starting materials, intermediates or major products, where applicable. Clearly indicate the stereochemistry if necessary.

HO
(0)
OH
PMBO
3. (a) KH, THF, 0°C
(b) PhCH₂Br
OH
1. DHP, cat. H*
3. PCC,
CH₂C₂2
1. TBSOTf,
2,6-lutidine,
CH₂Cl₂
CO₂Me
2. (a) LIAIH4, THF
(b) NaOH, H₂O
4. H*, H₂O
5. Jones Oxidation
roglar
OH
2. DDQ,
pH 7 buffer,
CH₂C₂2
Transcribed Image Text:HO (0) OH PMBO 3. (a) KH, THF, 0°C (b) PhCH₂Br OH 1. DHP, cat. H* 3. PCC, CH₂C₂2 1. TBSOTf, 2,6-lutidine, CH₂Cl₂ CO₂Me 2. (a) LIAIH4, THF (b) NaOH, H₂O 4. H*, H₂O 5. Jones Oxidation roglar OH 2. DDQ, pH 7 buffer, CH₂C₂2
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