Complete the curved arrow pushing mechanism of the reaction of butanal in ethylene glycol and hydrogen chloride by adding any missing curved arrows. A generic base, B:, is used as a proton shuttle. Step 1: Add curved arrows. Select Draw Templates More :: : Cl H G Select Draw Templates More C H O Cl → Step 3: add curved arrows. Recall that B: represents a generic base. :J: : 0: C H O : OH H Cl H 2 Q B Erase Erase OH : B Ⓡ 2 Q 11 Step 2: add curved arrows. Select Draw Templates More : Step 4: add curved arrows. C H O : Cl Select Draw Templates More → : 5: C H Cl O H Q2 Cl الر کرد B Erase O Erase HB + OH 2 Q
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
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