COMPARING THE OLD AND NEW AUFBAU 1. Write the electron configuration for the lead (Pb) atom with both the Old Aufbau and the New Aufbau diagrams. 2. Explain how this change to the newelectron configuration would affect the number of valence electrons in lead.
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
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BIUA
11
2 .3
9.
"Old" Auf Bau Principle
Diagram
"NEW"Auf Bau Principle
Diagram
Is?
1s
2s 2p
2s 2p"
3p
As 4p 4d10 4f'4
3d1o
3s 3p 3d10
4s 4p 4d 4f4
5s 5p 5d1" 5f'4 --
5s 5p 5d10 5f14..
6s 6p 6d0 ...
6s 6p 6d" ..
Assuming all other rules (Hund's, Pauli, etc).
COMPARING THE OLD AND NEW AUFBAU
1.
Write the electron configuration for the lead (Pb) atom with both the Old Aufbau and the
New Aufbau diagrams.
2. Explain how this change to the new electron configuration would affect the number of
valence electrons in lead.
Using the NEW AUFBAU:
The new aufbau diagram changes the number of valence electrons in many atoms. This is going
to change the arrangement of the periodic table.
3. Use pattems of electron configuration and Lewis structures found in the periodic table
(see the corresponding ChemQuests) to revise the arrangement of the first 36 elements
so that the same patterns exist (elements should still be listed in order of atomic
number).
Make sure that you explain your logic and use examples to justify your choices, including
which elements are first and last in each row.
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