[Co(CN):(OH;)J* + [Co(NH3)s(NCS)}* = [Co(CN):(SCN)]* + [Co(OH,);F* 3. Explain why, in the products of this reaction, one of the cobalt centers has lost all of the ammonia ligands initially attached to it.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
[Co(CN):(OH,))* + [Co(NH,)s(NCS)}* = [Co(CN):(SCN)J* + [Co(OH,)JF*
3. Explain why, in the products of this reaction, one of the cobalt centers has lost ll
of the ammonia ligands initially attached to it.
4. Draw the Lewis structure for the SCN' ligand and explain the two different ways
that it can function as a bridging ligand.
5. In the redox reactions between [Co(CN):(OH2)J®* and both linkage isomers of
[Co(NH3)s(SCN)]**, [[Co(CN);(SCN)]* is one of the products formed. Please draw
the two different bridged intermediates (one that results from the reaction of each
linkage isomer) that lead to the single S-bonded product.
6. In the redox reaction between [Co(NH3)(SCN)]²* and [Cr(OH2)]*, both remote
and adjacent attack on the SCN' ligand can occur, resulting in the formation of
[Cr(OH;)s(NCS)]** and [Cr(OH)s(SCN)]*, respectively. When [Co(NH3)s(NCS)]}*
is used, only [Cr(OH)s(SCN)]²* is formed. Please explain these results.
Transcribed Image Text:[Co(CN):(OH,))* + [Co(NH,)s(NCS)}* = [Co(CN):(SCN)J* + [Co(OH,)JF* 3. Explain why, in the products of this reaction, one of the cobalt centers has lost ll of the ammonia ligands initially attached to it. 4. Draw the Lewis structure for the SCN' ligand and explain the two different ways that it can function as a bridging ligand. 5. In the redox reactions between [Co(CN):(OH2)J®* and both linkage isomers of [Co(NH3)s(SCN)]**, [[Co(CN);(SCN)]* is one of the products formed. Please draw the two different bridged intermediates (one that results from the reaction of each linkage isomer) that lead to the single S-bonded product. 6. In the redox reaction between [Co(NH3)(SCN)]²* and [Cr(OH2)]*, both remote and adjacent attack on the SCN' ligand can occur, resulting in the formation of [Cr(OH;)s(NCS)]** and [Cr(OH)s(SCN)]*, respectively. When [Co(NH3)s(NCS)]}* is used, only [Cr(OH)s(SCN)]²* is formed. Please explain these results.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY