Determine if each of the following metal complexes is chi- ral and therefore has an optical isomer: (a) square planar [Pd(en)(CN),], (b) octahedral [Ni(en)(NH,),]²*, (C) octahe- dral cis-[V(en),CIB1].
Determine if each of the following metal complexes is chi- ral and therefore has an optical isomer: (a) square planar [Pd(en)(CN),], (b) octahedral [Ni(en)(NH,),]²*, (C) octahe- dral cis-[V(en),CIB1].
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 27P
Related questions
Question
![Determine if each of the following metal complexes is chi-
ral and therefore has an optical isomer: (a) square planar
[Pd(en)(CN),], (b) octahedral [Ni(en)(NH,),]²*, (C) octahe-
dral cis-[V(en),CIB1].](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F94b022a9-b424-4069-b54f-83a30664fd9c%2F0473b78b-281a-449e-8078-39d34a9aefe2%2Fohc50ve.png&w=3840&q=75)
Transcribed Image Text:Determine if each of the following metal complexes is chi-
ral and therefore has an optical isomer: (a) square planar
[Pd(en)(CN),], (b) octahedral [Ni(en)(NH,),]²*, (C) octahe-
dral cis-[V(en),CIB1].
Expert Solution
Step 1
EXPLANATION:
The optical isomers are the compounds in which arrangement of the substitutes in the three dimension is different.Chirality is a property of the compound in which the isomers are non-superimposable.
An optically active coordination compound shows optical isomers. Optical isomers are having same chemical formula and their mirror images are not superimposable on each other.
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