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CO, Reduction Products COSY Assignment Known Standards Chemical Shift H cross splitting coupling peaks "C "C "C (HSQC) (1D) splitting Probed Nucleus Product Name TH Chemical splitting Shift J coupling "C (10) 9.57 9.55 2.93 2.12 CHỊCH CHO CHCHO Propionaldehyde 9.57 209.6 8.33 172.2 171.76 HCOO Acetaldehyde Formate 9.55 2.93 206.9 8.33 171.77 161.16 Bicarbonate Electrolyte 162.97 130.74 Phenol Internal Standard 7.2 7.61 130.7 121.24 Phenol Internal Standard t 6.86 7.61 121.07 115.92 Phenol Internal Standard d 6.8 8.78 116.31 5.89 m 5.16, 5.06, 3.99 137.4 137.79 dd 5.16 17.57 5.13 4.68 5.89,3.99 1.21 dd 116.36 d CH,CHCH,OH CH,CHCH,OH Allyl Alcohol m 5.9 136.86 Allyl Alcohol 5.17 17.33 115.74 88.67 d 5.06 d 10.54 5.89, 3.99 116.36 d CH,CH(OH), CH,CHCH,OH Acetaldehyde 5.13 5.37 88.57 Allyl Alcohol d 5.07 10.5 115.74 4.94 5.27 3.4 90.6 d (OH),CHCH,OH Glycolaldehyde t 4.94 5.13 90.63 4.843 5.27 CH,CH,CH(OH), Propionaldehyde t 4.85 5.87 92.77 91.4 (OH), CHCH(OH), Glyoxal 91.39 WATER 4.25 S | CH,C(=O)C H₂OH | Hydroxyacetone 4.25 68.36 3.99 4.68 5.9, 5.15, 5.05 63.5 63.44 d CH,CHCOH Allyl Alcohol dt 3.99 5.13, 1.46 62.96 3.545 63.65 63.41 HOCHCH₂OH Ethylene Glycol 3.54 63.41 3.54 7.03 1.06 58.3 58.3 d CH,CH,OH Ethanol 3.53 7.32 58.3 3.44 7.03 1.42 64.35 64.42 d CH,CH,CH₂OH n-Propanol 3.44 6.49 64.43 3.4 4.68 4.94 65.6 65.38 d (OH), CHC,OH Glycolaldehyde d 3.4 5.13 65.42 3.23 49.85 49.76 CH₂OH Methanol S 3.23 49.75 2.44 7.03 37.25 DMSO CHỊCH CHỊU Internal Standard 2.6 39.6 Propionaldehyde σ 2.44 7.32 37.34 2.12 2.93 9.55 30.94 30.8 d | CH,CH=O Acetaldehyde d 2.12 2.93 30.89 2.1 30.9 CH,CHOCH₂ Acetone S 2.1 30.44 2.02 25.3 CH,C(=O)CH,OH Hydroxyacetone S 2.02 25.63 1.79 24 24.19 |CH,C(=O)0 Acetate 1.87 23.74 1.48 dt 5.85 30.95 CH,CH,CH(OH), Propionaldehyde dt 1.47 7.57, 12.94 30.45 1.42 sextet 6.44 3.44,0.77 25.28 25.37 t CH,CH,CH,OH n-Propanol sextet 1.42 7.32 25.41 1.21 d 5.27 5.13 24 23.82 d CHCH(OH), Acetaldehyde d 1.2 5.37 23.5 1.06 7.03 3.54 17.4 17.62 d CH,CH,OH Ethanol t 1.06 7.08 17.63 0.92 7.61 5.74 сискусно Propionaldehyde t 0.92 7.32 5.54 0.78 t 7.61 CHCH CH(OH), Propionaldehyde t 0.78 7.32 8.47 0.77 7.61 1.42 10.2 10.34 CH,CH,CH,OH n-Propanol 0.77 7.57 10.36

CO, Reduction Products COSY Assignment Known Standards Chemical Shift H cross splitting coupling peaks "C "C "C (HSQC) (1D) splitting Probed Nucleus Product Name TH Chemical splitting Shift J coupling "C (10) 9.57 9.55 2.93 2.12 CHỊCH CHO CHCHO Propionaldehyde 9.57 209.6 8.33 172.2 171.76 HCOO Acetaldehyde Formate 9.55 2.93 206.9 8.33 171.77 161.16 Bicarbonate Electrolyte 162.97 130.74 Phenol Internal Standard 7.2 7.61 130.7 121.24 Phenol Internal Standard t 6.86 7.61 121.07 115.92 Phenol Internal Standard d 6.8 8.78 116.31 5.89 m 5.16, 5.06, 3.99 137.4 137.79 dd 5.16 17.57 5.13 4.68 5.89,3.99 1.21 dd 116.36 d CH,CHCH,OH CH,CHCH,OH Allyl Alcohol m 5.9 136.86 Allyl Alcohol 5.17 17.33 115.74 88.67 d 5.06 d 10.54 5.89, 3.99 116.36 d CH,CH(OH), CH,CHCH,OH Acetaldehyde 5.13 5.37 88.57 Allyl Alcohol d 5.07 10.5 115.74 4.94 5.27 3.4 90.6 d (OH),CHCH,OH Glycolaldehyde t 4.94 5.13 90.63 4.843 5.27 CH,CH,CH(OH), Propionaldehyde t 4.85 5.87 92.77 91.4 (OH), CHCH(OH), Glyoxal 91.39 WATER 4.25 S | CH,C(=O)C H₂OH | Hydroxyacetone 4.25 68.36 3.99 4.68 5.9, 5.15, 5.05 63.5 63.44 d CH,CHCOH Allyl Alcohol dt 3.99 5.13, 1.46 62.96 3.545 63.65 63.41 HOCHCH₂OH Ethylene Glycol 3.54 63.41 3.54 7.03 1.06 58.3 58.3 d CH,CH,OH Ethanol 3.53 7.32 58.3 3.44 7.03 1.42 64.35 64.42 d CH,CH,CH₂OH n-Propanol 3.44 6.49 64.43 3.4 4.68 4.94 65.6 65.38 d (OH), CHC,OH Glycolaldehyde d 3.4 5.13 65.42 3.23 49.85 49.76 CH₂OH Methanol S 3.23 49.75 2.44 7.03 37.25 DMSO CHỊCH CHỊU Internal Standard 2.6 39.6 Propionaldehyde σ 2.44 7.32 37.34 2.12 2.93 9.55 30.94 30.8 d | CH,CH=O Acetaldehyde d 2.12 2.93 30.89 2.1 30.9 CH,CHOCH₂ Acetone S 2.1 30.44 2.02 25.3 CH,C(=O)CH,OH Hydroxyacetone S 2.02 25.63 1.79 24 24.19 |CH,C(=O)0 Acetate 1.87 23.74 1.48 dt 5.85 30.95 CH,CH,CH(OH), Propionaldehyde dt 1.47 7.57, 12.94 30.45 1.42 sextet 6.44 3.44,0.77 25.28 25.37 t CH,CH,CH,OH n-Propanol sextet 1.42 7.32 25.41 1.21 d 5.27 5.13 24 23.82 d CHCH(OH), Acetaldehyde d 1.2 5.37 23.5 1.06 7.03 3.54 17.4 17.62 d CH,CH,OH Ethanol t 1.06 7.08 17.63 0.92 7.61 5.74 сискусно Propionaldehyde t 0.92 7.32 5.54 0.78 t 7.61 CHCH CH(OH), Propionaldehyde t 0.78 7.32 8.47 0.77 7.61 1.42 10.2 10.34 CH,CH,CH,OH n-Propanol 0.77 7.57 10.36

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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pick a set of ethanol and methanol from the list in the picutre and provide simulations of 2D NMR (H-H COSY and HSQC). It would be a total of 4 2D simulations

CO, Reduction Products COSY Assignment Known Standards Chemical Shift H cross splitting coupling peaks "C "C "C (HSQC) (1D) splitting Probed Nucleus Product Name TH Chemical splitting Shift J coupling "C (10) 9.57 9.55 2.93 2.12 CHỊCH CHO CHCHO Propionaldehyde 9.57 209.6 8.33 172.2 171.76 HCOO Acetaldehyde Formate 9.55 2.93 206.9 8.33 171.77 161.16 Bicarbonate Electrolyte 162.97 130.74 Phenol Internal Standard 7.2 7.61 130.7 121.24 Phenol Internal Standard t 6.86 7.61 121.07 115.92 Phenol Internal Standard d 6.8 8.78 116.31 5.89 m 5.16, 5.06, 3.99 137.4 137.79 dd 5.16 17.57 5.13 4.68 5.89,3.99 1.21 dd 116.36 d CH,CHCH,OH CH,CHCH,OH Allyl Alcohol m 5.9 136.86 Allyl Alcohol 5.17 17.33 115.74 88.67 d 5.06 d 10.54 5.89, 3.99 116.36 d CH,CH(OH), CH,CHCH,OH Acetaldehyde 5.13 5.37 88.57 Allyl Alcohol d 5.07 10.5 115.74 4.94 5.27 3.4 90.6 d (OH),CHCH,OH Glycolaldehyde t 4.94 5.13 90.63 4.843 5.27 CH,CH,CH(OH), Propionaldehyde t 4.85 5.87 92.77 91.4 (OH), CHCH(OH), Glyoxal 91.39 WATER 4.25 S | CH,C(=O)C H₂OH | Hydroxyacetone 4.25 68.36 3.99 4.68 5.9, 5.15, 5.05 63.5 63.44 d CH,CHCOH Allyl Alcohol dt 3.99 5.13, 1.46 62.96 3.545 63.65 63.41 HOCHCH₂OH Ethylene Glycol 3.54 63.41 3.54 7.03 1.06 58.3 58.3 d CH,CH,OH Ethanol 3.53 7.32 58.3 3.44 7.03 1.42 64.35 64.42 d CH,CH,CH₂OH n-Propanol 3.44 6.49 64.43 3.4 4.68 4.94 65.6 65.38 d (OH), CHC,OH Glycolaldehyde d 3.4 5.13 65.42 3.23 49.85 49.76 CH₂OH Methanol S 3.23 49.75 2.44 7.03 37.25 DMSO CHỊCH CHỊU Internal Standard 2.6 39.6 Propionaldehyde σ 2.44 7.32 37.34 2.12 2.93 9.55 30.94 30.8 d | CH,CH=O Acetaldehyde d 2.12 2.93 30.89 2.1 30.9 CH,CHOCH₂ Acetone S 2.1 30.44 2.02 25.3 CH,C(=O)CH,OH Hydroxyacetone S 2.02 25.63 1.79 24 24.19 |CH,C(=O)0 Acetate 1.87 23.74 1.48 dt 5.85 30.95 CH,CH,CH(OH), Propionaldehyde dt 1.47 7.57, 12.94 30.45 1.42 sextet 6.44 3.44,0.77 25.28 25.37 t CH,CH,CH,OH n-Propanol sextet 1.42 7.32 25.41 1.21 d 5.27 5.13 24 23.82 d CHCH(OH), Acetaldehyde d 1.2 5.37 23.5 1.06 7.03 3.54 17.4 17.62 d CH,CH,OH Ethanol t 1.06 7.08 17.63 0.92 7.61 5.74 сискусно Propionaldehyde t 0.92 7.32 5.54 0.78 t 7.61 CHCH CH(OH), Propionaldehyde t 0.78 7.32 8.47 0.77 7.61 1.42 10.2 10.34 CH,CH,CH,OH n-Propanol 0.77 7.57 10.36
Transcribed Image Text:CO, Reduction Products COSY Assignment Known Standards Chemical Shift H cross splitting coupling peaks "C "C "C (HSQC) (1D) splitting Probed Nucleus Product Name TH Chemical splitting Shift J coupling "C (10) 9.57 9.55 2.93 2.12 CHỊCH CHO CHCHO Propionaldehyde 9.57 209.6 8.33 172.2 171.76 HCOO Acetaldehyde Formate 9.55 2.93 206.9 8.33 171.77 161.16 Bicarbonate Electrolyte 162.97 130.74 Phenol Internal Standard 7.2 7.61 130.7 121.24 Phenol Internal Standard t 6.86 7.61 121.07 115.92 Phenol Internal Standard d 6.8 8.78 116.31 5.89 m 5.16, 5.06, 3.99 137.4 137.79 dd 5.16 17.57 5.13 4.68 5.89,3.99 1.21 dd 116.36 d CH,CHCH,OH CH,CHCH,OH Allyl Alcohol m 5.9 136.86 Allyl Alcohol 5.17 17.33 115.74 88.67 d 5.06 d 10.54 5.89, 3.99 116.36 d CH,CH(OH), CH,CHCH,OH Acetaldehyde 5.13 5.37 88.57 Allyl Alcohol d 5.07 10.5 115.74 4.94 5.27 3.4 90.6 d (OH),CHCH,OH Glycolaldehyde t 4.94 5.13 90.63 4.843 5.27 CH,CH,CH(OH), Propionaldehyde t 4.85 5.87 92.77 91.4 (OH), CHCH(OH), Glyoxal 91.39 WATER 4.25 S | CH,C(=O)C H₂OH | Hydroxyacetone 4.25 68.36 3.99 4.68 5.9, 5.15, 5.05 63.5 63.44 d CH,CHCOH Allyl Alcohol dt 3.99 5.13, 1.46 62.96 3.545 63.65 63.41 HOCHCH₂OH Ethylene Glycol 3.54 63.41 3.54 7.03 1.06 58.3 58.3 d CH,CH,OH Ethanol 3.53 7.32 58.3 3.44 7.03 1.42 64.35 64.42 d CH,CH,CH₂OH n-Propanol 3.44 6.49 64.43 3.4 4.68 4.94 65.6 65.38 d (OH), CHC,OH Glycolaldehyde d 3.4 5.13 65.42 3.23 49.85 49.76 CH₂OH Methanol S 3.23 49.75 2.44 7.03 37.25 DMSO CHỊCH CHỊU Internal Standard 2.6 39.6 Propionaldehyde σ 2.44 7.32 37.34 2.12 2.93 9.55 30.94 30.8 d | CH,CH=O Acetaldehyde d 2.12 2.93 30.89 2.1 30.9 CH,CHOCH₂ Acetone S 2.1 30.44 2.02 25.3 CH,C(=O)CH,OH Hydroxyacetone S 2.02 25.63 1.79 24 24.19 |CH,C(=O)0 Acetate 1.87 23.74 1.48 dt 5.85 30.95 CH,CH,CH(OH), Propionaldehyde dt 1.47 7.57, 12.94 30.45 1.42 sextet 6.44 3.44,0.77 25.28 25.37 t CH,CH,CH,OH n-Propanol sextet 1.42 7.32 25.41 1.21 d 5.27 5.13 24 23.82 d CHCH(OH), Acetaldehyde d 1.2 5.37 23.5 1.06 7.03 3.54 17.4 17.62 d CH,CH,OH Ethanol t 1.06 7.08 17.63 0.92 7.61 5.74 сискусно Propionaldehyde t 0.92 7.32 5.54 0.78 t 7.61 CHCH CH(OH), Propionaldehyde t 0.78 7.32 8.47 0.77 7.61 1.42 10.2 10.34 CH,CH,CH,OH n-Propanol 0.77 7.57 10.36
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