CO + 2H2 −→ CH3OH The fresh feed to a methanol reactor contains 32.0 mole% CO, 64.0% H2 and 4% N2 and flows at a rate of 100 mol h−1 . The fresh feed is mixed with a recycle stream flowing at a rate of 400 mol h−1 to produce a reactor feed containing 13.0 mole% N2. The reactor outlet stream is fed to a condenser from which liquid methanol is removed. To control N2 buildup, a purge stream is withdrawn from the gas stream leaving the condenser. The gases not purged constitute the stream recycled to the reactor. (i)

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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3. Methanol can be produced from synthesis gas by the following reaction:
CO + 2H2 −→ CH3OH
The fresh feed to a methanol reactor contains 32.0 mole% CO, 64.0% H2 and 4% N2 and flows at a rate of
100 mol h−1
. The fresh feed is mixed with a recycle stream flowing at a rate of 400 mol h−1
to produce a
reactor feed containing 13.0 mole% N2. The reactor outlet stream is fed to a condenser from which liquid
methanol is removed. To control N2 buildup, a purge stream is withdrawn from the gas stream leaving the
condenser. The gases not purged constitute the stream recycled to the reactor.
(i) Draw a properly labelled diagram to illustrate the process.
(ii) Calculate the production rate of liquid methanol (mol h−1
)
(iii) Calculate the molar flow rate and composition of the purge gas.
(iv) Calculate the overall and single pass conversions.

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