clearly indicate your assignments of all pro 1.37 17. Draw the structures of Compound 17a. and 17b. resonances Calculate the Unsaturation Index of each Compound ( b = 1.37 ppm, singlet, 9H Compound 17a. CH,O, Unsat. Index = (2C + 2-H-X+ N/2 = a= 11.28 ppm, singlet, 1H 8, ppm 112 4.0 3.5 3.0 2.5 2.0 7.0 6.0 5.5 5.0 4.5 da is ie 0s do s 9085 80 7.5 6.5 1) SOCl2; 2) NH3 (excess) ! 3) Br2, NaOH, H2O 1.15 b= 1.15 ppm, singlet, 9H Compound 17b. C,H,,N Unsat Index = (2C + 2-H-X+N)2 = a = 3.96 ppm, singlet, 2H 8, ppm 3.96 9.5 9.0 8.5 80 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter22: Reactions Of Benzene And Its Derivatives
Section: Chapter Questions
Problem 22.10P: Addition of m-xylene to the strongly acidic solvent HF/SbF5 at 45C gives a new species, which shows...
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3
1.37
clearly indicate your assignments of all proton
17. Draw the structures of Compound 17a. and 17b.
resonances
Calculate the Unsaturation Index of each Compound (
b = 1.37 ppm,
singlet, 9H
Compound 17a. CH,O,
Unsat. Index = (2C + 2-H-X+ N/2 =
a= 11.28 ppm,
singlet, 1H
6, ppm
112
2.5
2.0
1.5
4.0
3.5
3.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
da is ne 1s do s
1) SOCl2; 2) NH3 (excess) ! 3) Br2, NaOH, H2O
1.15
b= 1.15 ppm,
singlet, 9H
Compound 17b. C,H,,N
Unsat Index = (2C + 2-H-X+N)2 =
a = 3.96 ppm,
singlet, 2H
8, ppm
10.5
3.96
95
9.0
8.5
80
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0
Transcribed Image Text:1.37 clearly indicate your assignments of all proton 17. Draw the structures of Compound 17a. and 17b. resonances Calculate the Unsaturation Index of each Compound ( b = 1.37 ppm, singlet, 9H Compound 17a. CH,O, Unsat. Index = (2C + 2-H-X+ N/2 = a= 11.28 ppm, singlet, 1H 6, ppm 112 2.5 2.0 1.5 4.0 3.5 3.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 da is ne 1s do s 1) SOCl2; 2) NH3 (excess) ! 3) Br2, NaOH, H2O 1.15 b= 1.15 ppm, singlet, 9H Compound 17b. C,H,,N Unsat Index = (2C + 2-H-X+N)2 = a = 3.96 ppm, singlet, 2H 8, ppm 10.5 3.96 95 9.0 8.5 80 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0
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