Clausius–Clapeyron equation: -AHvap In P = RT

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Suppose the vapor pressure of a substance is measured at two
different temperatures. (a) By using the Clausius–Clapeyron
equation (Equation 11.1) derive the following relationship
between the vapor pressures, P1 and P2, and the absolute temperatures
at which they were measured, T1 and T2:

 

(b) Gasoline is a mixture of hydrocarbons, a component
of which is octane (CH3CH2CH2CH2CH2CH2CH2CH3).

Octane has a vapor pressure of 13.95 torr at 25 °C and a vapor
pressure of 144.78 torr at 75 °C. Use these data and the equation
in part (a) to calculate the heat of vaporization of octane.
(c) By using the equation in part (a) and the data given in part
(b), calculate the normal boiling point of octane. Compare
your answer to the one you obtained from Exercise 11.81.
(d) Calculate the vapor pressure of octane at -30 °C.

 

Clausius–Clapeyron equation:
-AHvap
In P =
RT
Transcribed Image Text:Clausius–Clapeyron equation: -AHvap In P = RT
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