Classify the statements based on whether they describe the method of standard addition, the method of external calibration, or both.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Classify the statements based on whether they describe the method of standard addition, the method of external calibration, or both.

Ⓒ Macmillan Learning
Classify the statements based on whether they describe the method of standard addition, the method of external calibration,
or both.
Standard addition
Known quantities of a standard solution of
the analyte are added to the unknown.
It is the method of choice when the matrix of
the sample may affect the signal.
External calibration
It consists of a series of standard analyte
solutions separate from the unknown.
Matrix effects can cause the same analyte
concentration in an unknown and standard to
give different responses.
The response of the instrument must be linear
in the sample matrix.
Both
It is used to measure the instrument response
as a function of a known analyte
concentration under a set of conditions.
A blank is used to correct the response from
the instrument.
Systematic errors can occur due to sample or
standard preparation.
Transcribed Image Text:Ⓒ Macmillan Learning Classify the statements based on whether they describe the method of standard addition, the method of external calibration, or both. Standard addition Known quantities of a standard solution of the analyte are added to the unknown. It is the method of choice when the matrix of the sample may affect the signal. External calibration It consists of a series of standard analyte solutions separate from the unknown. Matrix effects can cause the same analyte concentration in an unknown and standard to give different responses. The response of the instrument must be linear in the sample matrix. Both It is used to measure the instrument response as a function of a known analyte concentration under a set of conditions. A blank is used to correct the response from the instrument. Systematic errors can occur due to sample or standard preparation.
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