Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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write a complete arrow-pushing mechanism for the synthesis of cyalume.
Transcribed Image Text:**Synthesis of Cyalume: Reaction Mechanism**
**Objective:** Using ChemDraw, write a complete arrow-pushing mechanism for the synthesis of cyalume.
**Reaction Overview:**
- **Reactants:**
- A chlorinated phenol and a chlorinated acyl chloride.
- Structures:
1. Chlorinated Phenol:
- Molecular structure: Benzene ring with OH group and three Cl atoms at alternating positions.
2. Chlorinated Acyl Chloride:
- Molecular structure: Two carbonyl groups (C=O) with Cl atoms attached to both ends.
- **Reagent:**
- Trimethylamine (NMe₃)
- **Solvent and Conditions:**
- Solvent: Toluene
- Temperature: 0°C to 75°C
**Product:**
- Structure: Benzofuran derivative
- The product formed consists of a fused ring structure featuring a benzene and furan ring, with multiple chlorine substituents.
The diagram depicts the transformation of reactants into the cyalume product via nucleophilic substitution, facilitated by trimethylamine in the presence of toluene, with the reaction proceeding from a lower to higher temperature.
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