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CI -D А - НзО+ B- H9SO4/H3O* C- 1. Li/pentane 2. D20 D- H2/Pt E- Li/NH3 F- 1. BH3/THF 2. H2O2/OH-

CI -D А - НзО+ B- H9SO4/H3O* C- 1. Li/pentane 2. D20 D- H2/Pt E- Li/NH3 F- 1. BH3/THF 2. H2O2/OH-

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Select the correct reagent/s for carrying out each of the following reactions shown below. Put a letter in each box.

This image provides a visual representation of chemical reactions with specific reagents and their resulting products. 1. **Top Reaction**: - **Reactant**: A terminal alkyne (1-butyne). - **Product**: A ketone (butanone). - **Reagent Options**: The reagents likely used in this reaction are option B – HgSO₄/H₃O⁺. This indicates an oxymercuration-demercuration process that converts the alkyne to a ketone. 2. **Middle Reaction**: - **Reactant**: A phenyl-substituted terminal alkyne (phenylacetylene). - **Product**: A conjugated diene (styrene). - **Reagent Options**: The conversion suggests the use of option E – Li/NH₃, which typically results in the partial reduction of alkynes to trans-alkenes. 3. **Bottom Reaction**: - **Reactant**: A chlorocyclohexane. - **Product**: A deuterated cycloalkane (cyclohexane-d). - **Reagent Options**: Reagents used here are likely C – 1. Li/pentane, 2. D₂O. This process involves the reduction of the alkyl halide using lithium and the introduction of deuterium through D₂O. **Reagent Key**: - **A**: H₃O⁺ - **B**: HgSO₄/H₃O⁺ - **C**: 1. Li/pentane 2. D₂O - **D**: H₂/Pt - **E**: Li/NH₃ - **F**: 1. BH₃/THF 2. H₂O₂/OH⁻ These reactions highlight various chemical transformations involving reduction, hydration, and deuteration processes using specific reagents.
Transcribed Image Text:This image provides a visual representation of chemical reactions with specific reagents and their resulting products. 1. **Top Reaction**: - **Reactant**: A terminal alkyne (1-butyne). - **Product**: A ketone (butanone). - **Reagent Options**: The reagents likely used in this reaction are option B – HgSO₄/H₃O⁺. This indicates an oxymercuration-demercuration process that converts the alkyne to a ketone. 2. **Middle Reaction**: - **Reactant**: A phenyl-substituted terminal alkyne (phenylacetylene). - **Product**: A conjugated diene (styrene). - **Reagent Options**: The conversion suggests the use of option E – Li/NH₃, which typically results in the partial reduction of alkynes to trans-alkenes. 3. **Bottom Reaction**: - **Reactant**: A chlorocyclohexane. - **Product**: A deuterated cycloalkane (cyclohexane-d). - **Reagent Options**: Reagents used here are likely C – 1. Li/pentane, 2. D₂O. This process involves the reduction of the alkyl halide using lithium and the introduction of deuterium through D₂O. **Reagent Key**: - **A**: H₃O⁺ - **B**: HgSO₄/H₃O⁺ - **C**: 1. Li/pentane 2. D₂O - **D**: H₂/Pt - **E**: Li/NH₃ - **F**: 1. BH₃/THF 2. H₂O₂/OH⁻ These reactions highlight various chemical transformations involving reduction, hydration, and deuteration processes using specific reagents.
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