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-CI -D A – H9SO4/H3O* B- 1. Li/pentane 2. D20 C- H2/Lindlar catalyst D - H2/Pt Е - 1. ВНз/ТHF 2. H2О2/ОН- F- D3O*

-CI -D A – H9SO4/H3O* B- 1. Li/pentane 2. D20 C- H2/Lindlar catalyst D - H2/Pt Е - 1. ВНз/ТHF 2. H2О2/ОН- F- D3O*

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Select the correct reagent/s for carrying out each of the following reactions shown below. Put a letter in each box.

CI -D A- H9SO4/H3O* B - 1. Li/pentane 2. D20 C- H2/Lindlar catalyst D - H2/Pt E - 1. BH3/THF 2. H2O2/OH F- D30*
Transcribed Image Text:CI -D A- H9SO4/H3O* B - 1. Li/pentane 2. D20 C- H2/Lindlar catalyst D - H2/Pt E - 1. BH3/THF 2. H2O2/OH F- D30*
Expert Solution
Step 1

A. HgSO4/H3O+ converts alkyne to ketone

B. 1. Li/Pentane 2. D2O This cause lithiation followed by deuteration to produce deuterated alkane

C. H2/Lindlar catalyst: Reduction of alkyne to cis-alkene

D. H2/Pt: Reduction of alkene/alkyne to alkane

E. 1. BH3/THF 2. H2O2/OH-: Overall causes hydration against the Markonikoff hydration

 

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