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CI 1. NaBD4 (excess), CH3OH 2. H₂O, HCI 1. NaBH4 (0.25 eq.), CH3OH 2. H₂O, HCI

CI 1. NaBD4 (excess), CH3OH 2. H₂O, HCI 1. NaBH4 (0.25 eq.), CH3OH 2. H₂O, HCI

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Sure, here is the transcribed text for an Educational website, along with detailed explanations of the diagrams: --- ## Organic Chemistry: Reduction Reactions ### Diagram 1 **Starting Compound:** Structure with an aromatic ring, a carboxylic acid (COOH) attached to the ring, and a carbonyl group (C=O) attached to the ring at a different position. **Reaction Conditions:** 1. **NaBH₄ (excess), CH₃OH** 2. **H₂O, HCl** **Description:** In this reaction, sodium borohydride (NaBH₄) is used in excess with methanol (CH₃OH) to reduce the carbonyl group. The presence of water (H₂O) and hydrochloric acid (HCl) assists in the reaction completion. --- ### Diagram 2 **Starting Compound:** Structure with an aromatic ring, an amide group (NH₂), a chloride (Cl) atom, and two carbonyl groups attached to the ring. **Reaction Conditions:** 1. **LiAlH₄ (excess), THF** 2. **H₂O, HCl** **Description:** Lithium aluminum hydride (LiAlH₄) is used in excess with tetrahydrofuran (THF) to reduce the carbonyl groups. Water (H₂O) and hydrochloric acid (HCl) are used for completion. --- ### Diagram 3 **Starting Compound:** Structure with an aromatic ring and two carbonyl groups attached to the ring. **Reaction Conditions:** 1. **NaBD₄ (excess), CH₃OH** 2. **H₂O, HCl** **Description:** In this reaction, sodium borodeuteride (NaBD₄) is used in excess with methanol (CH₃OH) to selectively reduce the carbonyl groups, with water and hydrochloric acid facilitating the process. --- ### Diagram 4 **Starting Compound:** Structure with an aromatic ring and a single carbonyl group at one position. **Reaction Conditions:** 1. **NaBH₄ (0.25 eq.), CH₃OH** 2. **H₂O, HCl** **Description:** Here, sodium borohydride (NaBH₄) is used with methanol (CH₃OH) in a limited quantity (
Transcribed Image Text:Sure, here is the transcribed text for an Educational website, along with detailed explanations of the diagrams: --- ## Organic Chemistry: Reduction Reactions ### Diagram 1 **Starting Compound:** Structure with an aromatic ring, a carboxylic acid (COOH) attached to the ring, and a carbonyl group (C=O) attached to the ring at a different position. **Reaction Conditions:** 1. **NaBH₄ (excess), CH₃OH** 2. **H₂O, HCl** **Description:** In this reaction, sodium borohydride (NaBH₄) is used in excess with methanol (CH₃OH) to reduce the carbonyl group. The presence of water (H₂O) and hydrochloric acid (HCl) assists in the reaction completion. --- ### Diagram 2 **Starting Compound:** Structure with an aromatic ring, an amide group (NH₂), a chloride (Cl) atom, and two carbonyl groups attached to the ring. **Reaction Conditions:** 1. **LiAlH₄ (excess), THF** 2. **H₂O, HCl** **Description:** Lithium aluminum hydride (LiAlH₄) is used in excess with tetrahydrofuran (THF) to reduce the carbonyl groups. Water (H₂O) and hydrochloric acid (HCl) are used for completion. --- ### Diagram 3 **Starting Compound:** Structure with an aromatic ring and two carbonyl groups attached to the ring. **Reaction Conditions:** 1. **NaBD₄ (excess), CH₃OH** 2. **H₂O, HCl** **Description:** In this reaction, sodium borodeuteride (NaBD₄) is used in excess with methanol (CH₃OH) to selectively reduce the carbonyl groups, with water and hydrochloric acid facilitating the process. --- ### Diagram 4 **Starting Compound:** Structure with an aromatic ring and a single carbonyl group at one position. **Reaction Conditions:** 1. **NaBH₄ (0.25 eq.), CH₃OH** 2. **H₂O, HCl** **Description:** Here, sodium borohydride (NaBH₄) is used with methanol (CH₃OH) in a limited quantity (
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