CHз - $—CH dimethyl sulfoxide I||| CI-C-C-CI oxalyl chloride CH3-S-CH3 + CO, + CO + Cr dimethylchloro- sulfonium ion

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Propose a mechanism to explain how dimethyl sulfoxide and oxalyl chloride react to form the dimethylchlorosulfonium ion used as the oxidizing agent in the Swern oxidation

CHз - $—CH
dimethyl sulfoxide
I|||
CI-C-C-CI
oxalyl chloride
CH3-S-CH3 + CO, + CO + Cr
dimethylchloro-
sulfonium ion
Transcribed Image Text:CHз - $—CH dimethyl sulfoxide I||| CI-C-C-CI oxalyl chloride CH3-S-CH3 + CO, + CO + Cr dimethylchloro- sulfonium ion
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