(CHs);CC(C6H5)3 2(CHs);C Time, t (sec) C/Co for hexaphenylethane 1.000 17.4 0.941 35.4 0.883 54.0 0.824 174.0 0.530 209 0.471 313 0.324 367 0.265 434 0.206 584 0.118 759 0.059

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The reaction of hexaphenyletane decomposing into triphenylmethyl radical in liquid chloroform was observed at temperature 0 celcius degree as follows.

Use graphical procedure to determine order of reaction, n and, reaction constant, k. and write the rate formula -rA=kCA^n

(CHs);CC(C6H5)3
2(CHs);C
Time, t (sec)
C/Co for hexaphenylethane
1.000
17.4
0.941
35.4
0.883
54.0
0.824
174.0
0.530
209
0.471
313
0.324
367
0.265
434
0.206
584
0.118
759
0.059
Transcribed Image Text:(CHs);CC(C6H5)3 2(CHs);C Time, t (sec) C/Co for hexaphenylethane 1.000 17.4 0.941 35.4 0.883 54.0 0.824 174.0 0.530 209 0.471 313 0.324 367 0.265 434 0.206 584 0.118 759 0.059
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