Chloride ions are added to the Ag|Ag* half-cell of the cell Ag|Ag*||Cu2|Cu to precipitate AgCl (s). The cell voltage is then measured to be +0.072 V at 298 K. If [Cu²*] = 1.0 M in the Cu2+|Cu half cell, what is [Ag*] in the Ag|Ag* half-cell? (First step: You will need to use the data in Table 17-1 to calculate E'cell.) Give your answer to two significant figures. Ecell = E°cell - (0.0257 V/n) In(Q) E'cell = E'ox + E°red
Chloride ions are added to the Ag|Ag* half-cell of the cell Ag|Ag*||Cu2|Cu to precipitate AgCl (s). The cell voltage is then measured to be +0.072 V at 298 K. If [Cu²*] = 1.0 M in the Cu2+|Cu half cell, what is [Ag*] in the Ag|Ag* half-cell? (First step: You will need to use the data in Table 17-1 to calculate E'cell.) Give your answer to two significant figures. Ecell = E°cell - (0.0257 V/n) In(Q) E'cell = E'ox + E°red
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![Chloride ions are added to the AglAg* half-cell of the cell
Ag|Ag*l|Cu²*|Cu to precipitate AgCI (s). The cell voltage is then
measured to be +0.072 V at 298 K. If [Cu2+] = 1.0 M in the Cu2+|Cu half
cell, what is [Ag*] in the Ag|Ag* half-cell? (First step: You will need to
use the data in Table 17-1 to calculate E°cell.) Give your answer to
two significant figures.
Ecell = E°cell - (0.0257 V/n) In(Q)
E'cell = E°ox + E°red](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe3e68242-5a91-4b54-b664-0ff90b744d38%2Fe5a5188e-682d-4f6f-b1ad-9145f22a7445%2Fseyjhck_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Chloride ions are added to the AglAg* half-cell of the cell
Ag|Ag*l|Cu²*|Cu to precipitate AgCI (s). The cell voltage is then
measured to be +0.072 V at 298 K. If [Cu2+] = 1.0 M in the Cu2+|Cu half
cell, what is [Ag*] in the Ag|Ag* half-cell? (First step: You will need to
use the data in Table 17-1 to calculate E°cell.) Give your answer to
two significant figures.
Ecell = E°cell - (0.0257 V/n) In(Q)
E'cell = E°ox + E°red
![cidic Solution, [H+] = 1M
CIO-(aq) + H2O + 2e-
Lit(aq) + e-
K+(aq) + e-
Ba2+(aq) + 2e-
Ca2+(aq) + 2e-
Na+(aq) + e-
Mg2+(aq) + 2e-
Al3+(aq) + 3e-
Mn2+(aq) + 2e
Zn2+(aq) + 2e-
Cr3+(aq) + 3e-
Fe2+(aq) + 2e-
Cr3+(aq) + e-
Cd2+(aq) + 2e-
PBSO4(s) + 2e-
TI+(aq) + e-
Co2+(aq) + 2e-
Ni2+(aq) + 2e-
Agl(s) + e-
Sn2+(aq) + 2e-
Pb2+(aq) + 2e-
2H+(aq) + 2e-
AgBr(s) + e-
S(s) + 2H+(aq) + 2e-
Sn4+(aq) + 2e-
SO.2-(aq) + 4H*(aq) + 2e-
Efed (V)
Li(s)
→K(s)
Ba(s)
→Ca(s)
Na(s)
→Mg(s)
Al(s)
→Mn(s)
→Zn(s)
Cr(s)
Fe(s)
Cr2+(aq)
Cd(s)
-3.040
Lithium is the strongest reducin
-2.936
-2.906
-2.869
-2.714
-2.357
-1.68
-1.182
-0.762
-0.744
-0.409
-0.408
-0.402
Pb(s) + SO,2-(aq)
TI(s)
Co(s)
Ni(s)
Ag(s) + 1-(aq)
Sn(s)
Pb(s)
-0.356
-0.336
->
-0.282
-0.236
-0.152
-0.141
-0.127
H2(g)
Ag(s) + Br(aq)
H2S(aq)
Sn2+(aq)
→SO2(g) + 2H2O
Cu*(aq)
Cu(s)
Cu(s)
21-(aq)
Fe2+(aq)
2Hg(1)
>Ag(s)
Hg2+(aq)
NO(g) + 2H20
→Au(s) + 4CI-(aq)
2Br(aq)
R
O = strongest oxidiz
0.000
R = strongest reduc
0.073
0.144
0.154
Cu2+(aq) + e-
Cu2+(aq) +.2e-
Cut(aq) + e-.
2(s) + 2e-
Fe3+ (aq).+ e-
Hg2 2+(aq) + 2e-
Ag+(aq) + e-
2H92+(aq) + 2e-
NO3-(aq) + 4H+(aq) + 3e-
AuCla-(aq) + 3e-
Br2(1) + 2e-
O2(g) + 4H+(aq) + 4e-
MnO2(s) + 4H+(aq) + 2e-
Cr20,2-(aq) + 14H+(aq) + 6e-
Cl2(g) + 2e-
CIO3-(aq) + 6H*(aq) + 5e¬
Au3+(ag) + Зе-
MnO4 (aq) + 8H+(aq) + 5e-
PbO2(s) + SO,2-(aq) + 4H*(aq) + 2e-
H2O2(aq) + 2H+(aq) + 2e-
Co3+ (aq) + e-
F2(g) + 2e-
0.155
->
0.161
0.339
0.518
0.534
0.769
0.796
0.799
0.908
0.964
1.001
1.077
2H20
1.229
1.229
→MN2+(aq) + 2H20
→2Cr3+(aq) + 7H20
→2CI-(aq)
Cb(g) + 3H20
Au(s)
Mn2+(aq) + 4H2O
PbSO4(s) + 2H2O
→2H20
Co2+(aq)
2F-(aq)
1.33
1.360
1.458
ban
1.498
1.512
1.687
1.763
1.953
2.889
Fluorine is the strongest c
Basic Solution, [OH-] = 1M
Efed (V)
-0.891
→Fe(s) + 20H-(aq)
→H2(g) + 20H-(aq)
Fe(OH)2(s) + OH-(aq)
-0.828
Fe(OH)2(s) + 2e-
2H20 + 2e-
Fe(OH)3(s) + e-
S(s) + 2e-
NO3-(ag) + 2H2O + 3e-
NO3 (ag) + H2O + 2e-
ClO4 (ag) + H2O + 2e
O>(g) + 2H20 + 4e-
CIo3 (ag) + 3H20+6e
-0.547
-0.445
Lithium and fluorine ard
ous materials to work
-0.140
NO(g) + 40H-(aq)
NO2 (aq) + 20H-(aq)
ClO, (aq) + 20H-(aq)
→4OH-(aq)
CI-(aq) + 60H-(aq)
CI-(aq) + 20H-(aq)
0.004
0.398
0.401
0.614
0.890
STANDARD
17.2
Increasing strength of oxidizing agents
Increasing strength of reducing agents](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe3e68242-5a91-4b54-b664-0ff90b744d38%2Fe5a5188e-682d-4f6f-b1ad-9145f22a7445%2Fyttja83_processed.jpeg&w=3840&q=75)
Transcribed Image Text:cidic Solution, [H+] = 1M
CIO-(aq) + H2O + 2e-
Lit(aq) + e-
K+(aq) + e-
Ba2+(aq) + 2e-
Ca2+(aq) + 2e-
Na+(aq) + e-
Mg2+(aq) + 2e-
Al3+(aq) + 3e-
Mn2+(aq) + 2e
Zn2+(aq) + 2e-
Cr3+(aq) + 3e-
Fe2+(aq) + 2e-
Cr3+(aq) + e-
Cd2+(aq) + 2e-
PBSO4(s) + 2e-
TI+(aq) + e-
Co2+(aq) + 2e-
Ni2+(aq) + 2e-
Agl(s) + e-
Sn2+(aq) + 2e-
Pb2+(aq) + 2e-
2H+(aq) + 2e-
AgBr(s) + e-
S(s) + 2H+(aq) + 2e-
Sn4+(aq) + 2e-
SO.2-(aq) + 4H*(aq) + 2e-
Efed (V)
Li(s)
→K(s)
Ba(s)
→Ca(s)
Na(s)
→Mg(s)
Al(s)
→Mn(s)
→Zn(s)
Cr(s)
Fe(s)
Cr2+(aq)
Cd(s)
-3.040
Lithium is the strongest reducin
-2.936
-2.906
-2.869
-2.714
-2.357
-1.68
-1.182
-0.762
-0.744
-0.409
-0.408
-0.402
Pb(s) + SO,2-(aq)
TI(s)
Co(s)
Ni(s)
Ag(s) + 1-(aq)
Sn(s)
Pb(s)
-0.356
-0.336
->
-0.282
-0.236
-0.152
-0.141
-0.127
H2(g)
Ag(s) + Br(aq)
H2S(aq)
Sn2+(aq)
→SO2(g) + 2H2O
Cu*(aq)
Cu(s)
Cu(s)
21-(aq)
Fe2+(aq)
2Hg(1)
>Ag(s)
Hg2+(aq)
NO(g) + 2H20
→Au(s) + 4CI-(aq)
2Br(aq)
R
O = strongest oxidiz
0.000
R = strongest reduc
0.073
0.144
0.154
Cu2+(aq) + e-
Cu2+(aq) +.2e-
Cut(aq) + e-.
2(s) + 2e-
Fe3+ (aq).+ e-
Hg2 2+(aq) + 2e-
Ag+(aq) + e-
2H92+(aq) + 2e-
NO3-(aq) + 4H+(aq) + 3e-
AuCla-(aq) + 3e-
Br2(1) + 2e-
O2(g) + 4H+(aq) + 4e-
MnO2(s) + 4H+(aq) + 2e-
Cr20,2-(aq) + 14H+(aq) + 6e-
Cl2(g) + 2e-
CIO3-(aq) + 6H*(aq) + 5e¬
Au3+(ag) + Зе-
MnO4 (aq) + 8H+(aq) + 5e-
PbO2(s) + SO,2-(aq) + 4H*(aq) + 2e-
H2O2(aq) + 2H+(aq) + 2e-
Co3+ (aq) + e-
F2(g) + 2e-
0.155
->
0.161
0.339
0.518
0.534
0.769
0.796
0.799
0.908
0.964
1.001
1.077
2H20
1.229
1.229
→MN2+(aq) + 2H20
→2Cr3+(aq) + 7H20
→2CI-(aq)
Cb(g) + 3H20
Au(s)
Mn2+(aq) + 4H2O
PbSO4(s) + 2H2O
→2H20
Co2+(aq)
2F-(aq)
1.33
1.360
1.458
ban
1.498
1.512
1.687
1.763
1.953
2.889
Fluorine is the strongest c
Basic Solution, [OH-] = 1M
Efed (V)
-0.891
→Fe(s) + 20H-(aq)
→H2(g) + 20H-(aq)
Fe(OH)2(s) + OH-(aq)
-0.828
Fe(OH)2(s) + 2e-
2H20 + 2e-
Fe(OH)3(s) + e-
S(s) + 2e-
NO3-(ag) + 2H2O + 3e-
NO3 (ag) + H2O + 2e-
ClO4 (ag) + H2O + 2e
O>(g) + 2H20 + 4e-
CIo3 (ag) + 3H20+6e
-0.547
-0.445
Lithium and fluorine ard
ous materials to work
-0.140
NO(g) + 40H-(aq)
NO2 (aq) + 20H-(aq)
ClO, (aq) + 20H-(aq)
→4OH-(aq)
CI-(aq) + 60H-(aq)
CI-(aq) + 20H-(aq)
0.004
0.398
0.401
0.614
0.890
STANDARD
17.2
Increasing strength of oxidizing agents
Increasing strength of reducing agents
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY