Reaction coordinate diagrams: Two-step diagram. Label the reactant (R), product (P), intermediate (I"), and transition states (TS; and TS2), plus the axis with appropriate units/labels. 1) Break the diagram up into 2 steps. Which one is the slow step? The fast step? 2) Endothermic or exothermic? Suppose a is added to step one. Sketch the effect of this addition on the diagram. You can identify the intermediates and by remembering: Intermediates are and then Catalysts are added to a reaction (like a reactant), and are at the end. Practice: Identify the reactants, products, intermediate(s), and catalyst(s). Put a star next to the rate-determining step. Step 1 A+B AB (fastest) Step 2 C + AB → ABC Step 3 ABC + D→ ACD + B (fast) diy

Chemistry for Engineering Students
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Chapter12: Chemical Equilibrium
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Problem 12.87PAE
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Reaction coordinate diagrams:
Two-step diagram. Label the reactant (R), product (P), intermediate (I"), and transition
states (TS; and TS2), plus the axis with appropriate units/labels.
1) Break the diagram up into 2
steps. Which one is the slow
step? The fast step?
2) Endothermic or exothermic?
Suppose a
is added to step one. Sketch the effect of this
addition on the diagram.
You can identify the intermediates and
by remembering:
Intermediates are
and then
Catalysts are added to a reaction (like a reactant), and are
at the end.
Practice: Identify the reactants, products, intermediate(s), and catalyst(s). Put a star next to
the rate-determining step.
Step 1
A+B AB
(fastest)
Step 2
C + AB → ABC
Step 3
ABC + D→ ACD + B
(fast)
diy
Transcribed Image Text:Reaction coordinate diagrams: Two-step diagram. Label the reactant (R), product (P), intermediate (I"), and transition states (TS; and TS2), plus the axis with appropriate units/labels. 1) Break the diagram up into 2 steps. Which one is the slow step? The fast step? 2) Endothermic or exothermic? Suppose a is added to step one. Sketch the effect of this addition on the diagram. You can identify the intermediates and by remembering: Intermediates are and then Catalysts are added to a reaction (like a reactant), and are at the end. Practice: Identify the reactants, products, intermediate(s), and catalyst(s). Put a star next to the rate-determining step. Step 1 A+B AB (fastest) Step 2 C + AB → ABC Step 3 ABC + D→ ACD + B (fast) diy
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