B Potential energy Reaction Reaction coordinate coordinate C D otential -nergy Potential energy h Reaction coordinate Reaction coordinate n diagrams correspond with a two-step mechanism? diagrams correspond with a ono otop Potential energy
B Potential energy Reaction Reaction coordinate coordinate C D otential -nergy Potential energy h Reaction coordinate Reaction coordinate n diagrams correspond with a two-step mechanism? diagrams correspond with a ono otop Potential energy
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Energy Diagrams Analysis
#### Consider the following four energy diagrams:
**Energy Diagrams:**
- **Diagram A:** A simple curve that rises to a peak and then falls back down.
- **Diagram B:** A curve with two peaks, indicating two distinct steps.
- **Diagram C:** Similar to Diagram A but with a different peak height.
- **Diagram D:** A curve with multiple peaks and valleys, suggesting a more complex mechanism.
#### Questions for Analysis:
1. **Which diagrams correspond with a two-step mechanism?**
Two-step mechanisms are indicated by diagrams with two distinct peaks. Therefore:
- Diagram B
2. **Which diagrams correspond with a one-step mechanism?**
One-step mechanisms are indicated by diagrams with a single peak. Therefore:
- Diagrams A and C
3. **Compare energy diagrams A and C. Which has a relatively larger Ea?**
- Diagram C has a higher peak than Diagram A, indicating a larger activation energy (Ea).
4. **Compare diagrams A and C. Which has a negative ΔG?**
- Diagram C ends lower than it starts, indicating a negative ΔG.
5. **Compare diagrams A and D. Which has a positive ΔG?**
- Diagram D ends higher than it starts, indicating a positive ΔG.
6. **Compare all four energy diagrams. Which one exhibits the largest Ea?**
- Diagram C exhibits the largest activation energy (Ea) as it has the highest peak.
7. **Which processes will have a value of Keq that is greater than 1?**
Processes with Keq greater than 1 will have a negative ΔG, meaning products are lower in energy than reactants. Therefore:
- Diagram C
8. **Which process will have a value of Keq that is roughly equal to 1?**
A process with Keq roughly equal to 1 will have products and reactants at almost the same energy level. Therefore:
- Diagram A
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