1. For a solution in which u = 8.0 x 102, calculate K'sp for Pbl2. The thermodynamic constant of the solubility constant of Pbl, is 7.9 x 10°. Use the linear interpolation of experimental data below. TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated Ionic Strength Ion ax, nm 0.001 0.005 0.01 0.05 0.1 H,O* Li*, CH,COO Na*, IO,", HSO,, HCO,, H,PO,, H,AsO,, OAc OH, F, SCN", HS", CIO,, CIO, , BrO,, IO,, MnO, K*, CI", Br", I, CN", NO,, NO,, HCOO Rb*, Cs*, TI*, Ag", NH, Mg**, Be* Ca, Cu, Zn*, Snt, Mn, Fe, Ni*, Co, Phthalate S*, Ba*, Cd*, Hg²*, S- Pb2+, CO,-, So,-, C,0, Hg,*, SO,, s,0,-, Cr, HPO, AP+, Fe*, Cr*, La, Ce* PO,, Fe(CN), Th**, Zr*, Ce**, Sn+ Fe(CN), 0.967 0.934 0.930 0.9 0.913 0.85 0.83 0.6 0.966 0.907 0.83 0.80 0.965 0.965 0.4-0.45 0.927 0.902 0.82 0.77 0.35 0.926 0.900 0.81 0.76 0.3 0.965 0.925 0.899 0.81 0.75 0.25 0.965 0.925 0.897 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.748 0.743 0.741 0.738 0.6 0.870 0.676 0.48 0.40 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.665 0.45 0.44 0.36 0.40 0.867 0.661 0.35 0.9 0.737 0.540 0.443 0.24 0.18 0.394 0.252 0.4 0.726 0.505 0.16 0.095 1.1 0.587 0.348 0.10 0.063 0.5 0.569 0.305 0.200 0.047 0.020

1. For a solution in which u = 8.0 x 102, calculate K'sp for Pbl2. The thermodynamic constant of the solubility constant of Pbl, is 7.9 x 10°. Use the linear interpolation of experimental data below. TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated Ionic Strength Ion ax, nm 0.001 0.005 0.01 0.05 0.1 H,O* Li, CH,COO Na, IO,", HSO,, HCO,, H,PO,, H,AsO,, OAc OH, F, SCN", HS", CIO,, CIO, , BrO,, IO,, MnO, K, CI", Br", I, CN", NO,, NO,, HCOO Rb, Cs, TI, Ag", NH, Mg**, Be* Ca, Cu, Zn, Snt, Mn, Fe, Ni, Co, Phthalate S, Ba, Cd, Hg², S- Pb2+, CO,-, So,-, C,0, Hg,, SO,, s,0,-, Cr, HPO, AP+, Fe, Cr, La, Ce PO,, Fe(CN), Th**, Zr*, Ce**, Sn+ Fe(CN), 0.967 0.934 0.930 0.9 0.913 0.85 0.83 0.6 0.966 0.907 0.83 0.80 0.965 0.965 0.4-0.45 0.927 0.902 0.82 0.77 0.35 0.926 0.900 0.81 0.76 0.3 0.965 0.925 0.899 0.81 0.75 0.25 0.965 0.925 0.897 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.748 0.743 0.741 0.738 0.6 0.870 0.676 0.48 0.40 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.665 0.45 0.44 0.36 0.40 0.867 0.661 0.35 0.9 0.737 0.540 0.443 0.24 0.18 0.394 0.252 0.4 0.726 0.505 0.16 0.095 1.1 0.587 0.348 0.10 0.063 0.5 0.569 0.305 0.200 0.047 0.020

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

1. For a solution in which u = 8.0 x 102, calculate K'sp for Pbl2. The thermodynamic constant of the
solubility constant of Pbl, is 7.9 x 10°. Use the linear interpolation of experimental data below.
TABLE 10-2
Activity Coefficients for Ions at 25°C
Activity Coefficient at Indicated Ionic Strength
Ion
ax, nm
0.001
0.005
0.01
0.05
0.1
H,O*
Li*, CH,COO
Na*, IO,", HSO,, HCO,, H,PO,, H,AsO,, OAc
OH, F, SCN", HS", CIO,, CIO, , BrO,, IO,, MnO,
K*, CI", Br", I, CN", NO,, NO,, HCOO
Rb*, Cs*, TI*, Ag", NH,
Mg**, Be*
Ca, Cu, Zn*, Snt, Mn, Fe, Ni*, Co, Phthalate
S*, Ba*, Cd*, Hg²*, S-
Pb2+, CO,-, So,-, C,0,
Hg,*, SO,, s,0,-, Cr, HPO,
AP+, Fe*, Cr*, La, Ce*
PO,, Fe(CN),
Th**, Zr*, Ce**, Sn+
Fe(CN),
0.967
0.934
0.930
0.9
0.913
0.85
0.83
0.6
0.966
0.907
0.83
0.80
0.965
0.965
0.4-0.45
0.927
0.902
0.82
0.77
0.35
0.926
0.900
0.81
0.76
0.3
0.965
0.925
0.899
0.81
0.75
0.25
0.965
0.925
0.897
0.80
0.75
0.8
0.872
0.756
0.690
0.52
0.44
0.748
0.743
0.741
0.738
0.6
0.870
0.676
0.48
0.40
0.5
0.869
0.668
0.46
0.38
0.45
0.868
0.665
0.45
0.44
0.36
0.40
0.867
0.661
0.35
0.9
0.737
0.540
0.443
0.24
0.18
0.394
0.252
0.4
0.726
0.505
0.16
0.095
1.1
0.587
0.348
0.10
0.063
0.5
0.569
0.305
0.200
0.047
0.020

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