Choose the best explanation for why -OH and -NH peaks are often broad singlets in a ¹H NMR spectrum. A) The greater electronegativity difference in the N-H or O-H bond compared to a C-H bond makes the peak broader. B) The greater mass involved in the N-H or O-H bond compared to a C-H bond makes the peak broader. C) The hydrogen nuclei on the carbon next to the -OH or -NH are too far away to impact the multiplicity. D) Protons in OH or NH groups are acidic enough to rapidly exchange between different molecules, so the coupling to vicinal hydrogens is not clearly observed.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 50AP: One way to determine the number of acidic hydrogens in a molecule is to treat the compound with NaOD...
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Choose the best explanation for why -OH and -NH peaks are often broad singlets
in a ¹H NMR spectrum.
A) The greater electronegativity difference in
the N-H or O-H bond compared to a C-H bond
makes the peak broader.
B) The greater mass involved in the N-H or O-H
bond compared to a C-H bond makes the peak
broader.
C) The hydrogen nuclei on the carbon next to
the -OH or -NH are too far away to impact the
multiplicity.
D) Protons in OH or NH groups are acidic
enough to rapidly exchange between different
molecules, so the coupling to vicinal hydrogens
is not clearly observed.
Transcribed Image Text:Choose the best explanation for why -OH and -NH peaks are often broad singlets in a ¹H NMR spectrum. A) The greater electronegativity difference in the N-H or O-H bond compared to a C-H bond makes the peak broader. B) The greater mass involved in the N-H or O-H bond compared to a C-H bond makes the peak broader. C) The hydrogen nuclei on the carbon next to the -OH or -NH are too far away to impact the multiplicity. D) Protons in OH or NH groups are acidic enough to rapidly exchange between different molecules, so the coupling to vicinal hydrogens is not clearly observed.
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