**Consider the decomposition of a metal oxide to its elements, where M represents a generic metal.** \[ \text{M}_2\text{O}_3(s) \rightleftharpoons 2 \text{M}(s) + \frac{3}{2} \text{O}_2(g) \] 1. **What is the standard change in Gibbs energy for the reaction, as written, in the forward direction?** \[ \Delta G^\circ_{\text{rxn}} = \underline{\hspace{3cm}} \text{ kJ/mol} \] 2. **What is the equilibrium constant of this reaction, as written, in the forward direction at 298 K?** \[ K = \underline{\hspace{6cm}} \] 3. **What is the equilibrium pressure of O\(_2\)(g) over M(s) at 298 K?** \[ P_{O_2} = \underline{\hspace{4cm}} \text{ atm} \] **Table: Standard Gibbs Energy of Formation \(\Delta G^\circ_f\) (kJ/mol)** \[ \begin{array}{|c|c|} \hline \text{Substance} & \Delta G^\circ_f \text{ (kJ/mol)} \\ \hline \text{M}_2\text{O}_3(s) & -9.80 \\ \text{M}(s) & 0 \\ \text{O}_2(g) & 0 \\ \hline \end{array} \] **Explanation of the Reaction:** - The chemical equation represents the decomposition of a metal oxide, \(\text{M}_2\text{O}_3\), into metal \(\text{M}\) and oxygen gas \(\text{O}_2\). - The balance of the equation ensures the conservation of mass. **Standard Gibbs Energy and Equilibrium Constant Calculations:** - The standard change in Gibbs energy (\(\Delta G^\circ_{\text{rxn}}\)) for the reaction can be calculated using the Gibbs energy values from the table. - The equilibrium constant \(K\) at 298 K can then be determined from \(\Delta G^\circ_{\text{rxn}}\) using the relation \( \Delta G
**Consider the decomposition of a metal oxide to its elements, where M represents a generic metal.** \[ \text{M}_2\text{O}_3(s) \rightleftharpoons 2 \text{M}(s) + \frac{3}{2} \text{O}_2(g) \] 1. **What is the standard change in Gibbs energy for the reaction, as written, in the forward direction?** \[ \Delta G^\circ_{\text{rxn}} = \underline{\hspace{3cm}} \text{ kJ/mol} \] 2. **What is the equilibrium constant of this reaction, as written, in the forward direction at 298 K?** \[ K = \underline{\hspace{6cm}} \] 3. **What is the equilibrium pressure of O\(_2\)(g) over M(s) at 298 K?** \[ P_{O_2} = \underline{\hspace{4cm}} \text{ atm} \] **Table: Standard Gibbs Energy of Formation \(\Delta G^\circ_f\) (kJ/mol)** \[ \begin{array}{|c|c|} \hline \text{Substance} & \Delta G^\circ_f \text{ (kJ/mol)} \\ \hline \text{M}_2\text{O}_3(s) & -9.80 \\ \text{M}(s) & 0 \\ \text{O}_2(g) & 0 \\ \hline \end{array} \] **Explanation of the Reaction:** - The chemical equation represents the decomposition of a metal oxide, \(\text{M}_2\text{O}_3\), into metal \(\text{M}\) and oxygen gas \(\text{O}_2\). - The balance of the equation ensures the conservation of mass. **Standard Gibbs Energy and Equilibrium Constant Calculations:** - The standard change in Gibbs energy (\(\Delta G^\circ_{\text{rxn}}\)) for the reaction can be calculated using the Gibbs energy values from the table. - The equilibrium constant \(K\) at 298 K can then be determined from \(\Delta G^\circ_{\text{rxn}}\) using the relation \( \Delta G
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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