**Reaction Order and Rate Constant Calculation** **Multiple Choice Options:** - **c.** The reaction is second order, and k is \(2.75 \times 10^{-3} \, \text{l/Ms}\). - **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\). - **e.** The reaction is first order, and k is \(-2.75 \times 10^{-3} \, \text{s}^{-1}\). **Selected Option:** - **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\). **Problem Description:** A **first order** reaction (\(A \rightarrow B\)) starts with an initial concentration \([A]_0 = 0.400 \, \text{M}\). After 2.25 seconds, the concentration \([A]\) is measured to be 0.060 M. Calculate the rate constant for the reaction. The answer should be in \(\text{s}^{-1}\) with three significant figures. **Provided Answer:** - **6.29** --- To solve this problem, one would typically use the first order reaction formula: \[ \ln\left(\frac{[A]_0}{[A]}\right) = kt \] Plugging in the values: - \([A]_0 = 0.400 \, \text{M}\) - \([A] = 0.060 \, \text{M}\) - \(t = 2.25 \, \text{s}\) The rate constant, \(k\), can be calculated as follows: \[ k = \frac{\ln\left(\frac{0.400}{0.060}\right)}{2.25} \] This calculation yields a rate constant, \(k\), consistent with the values expected of a correctly computed first order reaction rate constant.

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**Reaction Order and Rate Constant Calculation**

**Multiple Choice Options:**

- **c.** The reaction is second order, and k is \(2.75 \times 10^{-3} \, \text{l/Ms}\).
- **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\).
- **e.** The reaction is first order, and k is \(-2.75 \times 10^{-3} \, \text{s}^{-1}\).

**Selected Option:**

- **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\).

**Problem Description:**

A **first order** reaction (\(A \rightarrow B\)) starts with an initial concentration \([A]_0 = 0.400 \, \text{M}\). After 2.25 seconds, the concentration \([A]\) is measured to be 0.060 M. Calculate the rate constant for the reaction. The answer should be in \(\text{s}^{-1}\) with three significant figures.

**Provided Answer:**

- **6.29**

---

To solve this problem, one would typically use the first order reaction formula:

\[ \ln\left(\frac{[A]_0}{[A]}\right) = kt \]

Plugging in the values:

- \([A]_0 = 0.400 \, \text{M}\)
- \([A] = 0.060 \, \text{M}\)
- \(t = 2.25 \, \text{s}\)

The rate constant, \(k\), can be calculated as follows:

\[ k = \frac{\ln\left(\frac{0.400}{0.060}\right)}{2.25} \]

This calculation yields a rate constant, \(k\), consistent with the values expected of a correctly computed first order reaction rate constant.
Transcribed Image Text:**Reaction Order and Rate Constant Calculation** **Multiple Choice Options:** - **c.** The reaction is second order, and k is \(2.75 \times 10^{-3} \, \text{l/Ms}\). - **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\). - **e.** The reaction is first order, and k is \(-2.75 \times 10^{-3} \, \text{s}^{-1}\). **Selected Option:** - **d.** The reaction is first order, and k is \(2.75 \times 10^{-3} \, \text{s}^{-1}\). **Problem Description:** A **first order** reaction (\(A \rightarrow B\)) starts with an initial concentration \([A]_0 = 0.400 \, \text{M}\). After 2.25 seconds, the concentration \([A]\) is measured to be 0.060 M. Calculate the rate constant for the reaction. The answer should be in \(\text{s}^{-1}\) with three significant figures. **Provided Answer:** - **6.29** --- To solve this problem, one would typically use the first order reaction formula: \[ \ln\left(\frac{[A]_0}{[A]}\right) = kt \] Plugging in the values: - \([A]_0 = 0.400 \, \text{M}\) - \([A] = 0.060 \, \text{M}\) - \(t = 2.25 \, \text{s}\) The rate constant, \(k\), can be calculated as follows: \[ k = \frac{\ln\left(\frac{0.400}{0.060}\right)}{2.25} \] This calculation yields a rate constant, \(k\), consistent with the values expected of a correctly computed first order reaction rate constant.
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