### Chemical Reaction: Benzil to Hexan-2,5-dione #### Reactants: - **Benzil:** The structure on the left shows a benzene ring with two ketone groups on adjacent carbon atoms. #### Products: - **Hexan-2,5-dione:** The structure on the right is a linear six-carbon chain with ketone groups on the second and fifth carbon atoms. #### Reaction Conditions: - **Reagents:** Sodium hydroxide (NaOH) and ethanol (EtOH) - **Process:** Reflux #### Process Explanation: This transformation shows the conversion of benzil into hexan-2,5-dione under basic conditions using sodium hydroxide in an ethanol solvent. The process involves reflux, a technique where the reaction mixture is heated to boiling and the vapor is condensed back to liquid, allowing continuous heating without loss of solvent. --- This reaction exemplifies a rearrangement where a cyclic ketone is opened into a linear diketone under the influence of base catalysis.
### Chemical Reaction: Benzil to Hexan-2,5-dione #### Reactants: - **Benzil:** The structure on the left shows a benzene ring with two ketone groups on adjacent carbon atoms. #### Products: - **Hexan-2,5-dione:** The structure on the right is a linear six-carbon chain with ketone groups on the second and fifth carbon atoms. #### Reaction Conditions: - **Reagents:** Sodium hydroxide (NaOH) and ethanol (EtOH) - **Process:** Reflux #### Process Explanation: This transformation shows the conversion of benzil into hexan-2,5-dione under basic conditions using sodium hydroxide in an ethanol solvent. The process involves reflux, a technique where the reaction mixture is heated to boiling and the vapor is condensed back to liquid, allowing continuous heating without loss of solvent. --- This reaction exemplifies a rearrangement where a cyclic ketone is opened into a linear diketone under the influence of base catalysis.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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