12 Note: This is a 2 point question. The reaction below is first order with respect to NO and second order with respect to Cl, Determine the value of the rate constant and write the rate law. 14 15 2 NO + Cl2 (e) (2) → 2 NOCI (e) Initial [NO] Initial [Cl] Initial Rate (M/s) 18 Experiment 0.0255 -- 0.0125 M 2. 0.0125 M 0.0510 21 0.0250 M 0.0255 4.55 x 10-5 3. Rate = 0.00370 M2s- [NOe]? [Clze] to O Rate = 2.79 M25- [NO)] [Clze]! Rate = 0.0712 M's'[NO2] [Cl} O Rate = 5.70 M's' [NO2]' [Cll² Rate = 5.70 M²²s²1 [NO]² [Cly«]' %3D Rate = 2.79 M2s1 [NO]' [C»el° Rate = 0.00370 M2s [NO2(2)] [C2el* Rate = 0.0712 M's[NO2] [Cl2(g)]

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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12
Note: This is a 2 point question.
The reaction below is first order with respect to NO and second order with respect to
Cl, Determine the value of the rate constant and write the rate law.
14
15
2 NO
+ Cl2 (e)
(2)
→ 2 NOCI (e)
Initial [NO]
Initial [Cl]
Initial Rate (M/s)
18
Experiment
0.0255
--
0.0125 M
2.
0.0125 M
0.0510
21
0.0250 M
0.0255
4.55 x 10-5
3.
Rate = 0.00370 M2s- [NOe]? [Clze]
to
O Rate = 2.79 M25- [NO)] [Clze]!
Rate = 0.0712 M's'[NO2] [Cl}
O Rate = 5.70 M's' [NO2]' [Cll²
Rate = 5.70 M²²s²1 [NO]² [Cly«]'
%3D
Rate = 2.79 M2s1 [NO]' [C»el°
Rate = 0.00370 M2s [NO2(2)] [C2el*
Rate = 0.0712 M's[NO2] [Cl2(g)]
Transcribed Image Text:12 Note: This is a 2 point question. The reaction below is first order with respect to NO and second order with respect to Cl, Determine the value of the rate constant and write the rate law. 14 15 2 NO + Cl2 (e) (2) → 2 NOCI (e) Initial [NO] Initial [Cl] Initial Rate (M/s) 18 Experiment 0.0255 -- 0.0125 M 2. 0.0125 M 0.0510 21 0.0250 M 0.0255 4.55 x 10-5 3. Rate = 0.00370 M2s- [NOe]? [Clze] to O Rate = 2.79 M25- [NO)] [Clze]! Rate = 0.0712 M's'[NO2] [Cl} O Rate = 5.70 M's' [NO2]' [Cll² Rate = 5.70 M²²s²1 [NO]² [Cly«]' %3D Rate = 2.79 M2s1 [NO]' [C»el° Rate = 0.00370 M2s [NO2(2)] [C2el* Rate = 0.0712 M's[NO2] [Cl2(g)]
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