Chemiosmosis is a process that drives the creation of ATP. This process requires the use of specific enzymes which were unlikely to have existed on early Earth. A. What has this new study uncovered in relation to ATP on early Earth? B. How do scientists postulate that the phosphorus on early Earth was created? C. Explain why this study is important?
Chemiosmosis is a process that drives the creation of ATP. This process requires the use of specific enzymes which were unlikely to have existed on early Earth. A. What has this new study uncovered in relation to ATP on early Earth? B. How do scientists postulate that the phosphorus on early Earth was created? C. Explain why this study is important?
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
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Chemiosmosis is a process that drives the creation of ATP. This process requires the use of specific enzymes which were unlikely to have existed on early Earth.
A. What has this new study uncovered in relation to ATP on early Earth?
B. How do scientists postulate that the phosphorus on early Earth was created?
C. Explain why this study is important?

Transcribed Image Text:In their analysis of the resulting solution the scientists found the compound
pyrophosphite, a molecular 'cousin' of pyrophosphate -- the part of ATP
responsible for energy transfer. The scientists believe this compound could have
acted as an earlier form of ATP in what they have dubbed 'chemical life'.
"Chemical life would have been the intermediary step between inorganic rock
and the very first living biological cell. You could think of chemical life as a
machine -a robot, for example, is capable of moving and reacting to
surroundings, but it is not alive. With the aid of these primitive batteries,
chemicals became organised in such a way as to be capable of more complex
behaviour and would have eventually developed into the living biological
structures we see today," said Dr Terry Kee.
The team from NASA's Jet Propulsion Laboratory (JPL-Caltech) working on the
Curiosity rover, which landed on Mars in August last year, has recently reported
the presence of phosphorus on the Red Planet.
"If Curiosity has found phosphorus in one of the forms we produced in Iceland,
this may indicate that conditions on Mars were at one point suitable for the
development of life in much the same way we now believe it developed on
Earth," added Dr Kee.
The team at Leeds are now working with colleagues at JPL-Caltech to understand
how these early batteries and the 'chemical life' they became part of might have
developed into biological life. As part of this work they will be using facilities in
the University of Leeds' Faculty of Engineering, currently used to test new fuel
cells, to build a 'geological fuel cell' using minerals and gases common on the
early Earth. Researchers will apply different chemicals to its surface and monitor
the reactions take place and the chemical products which develop.
The team also hope to travel to Disko Island in Greenland which is home to the
Earth's only naturally-occurring source of schreibersite, the mineral found in the
Sikhote-Alin meteorite. Here, they hope to repeat their experiments and show
that the same chemicals develop in an entirely Earth-originated setting.
Story Source:
University of Leeds (2013, April 4). Origin of life: Power behind primordial soup discovered.
ScienceDaily. Retrieved June 4, 2013, from
http://www.sciencedaily.com/releases/2013/04/130404122234.htm
Journal Reference:
David E. Bryant, David Greenfield, Richard D. Walshaw, Benjamin R.G. Johnson, Barry Herschy,
Caroline Smith, Matthew A. Pasek, Richard Telford, lan Scowen, Tasnim Munshi, Howell G.M.
Edwards, Claire R. Cousins, lan A. Crawford, Terence P. Kee. Hydrothermal modification of the
Sikhote-Alin iron meteorite under low pH geothermal environments. A plausibly prebiotic route
to activated phosphorus on the early Earth. Geochimica et Cosmochimica Acta, 2013; 109: 90 DOI:
10.1016/j.gca.2012.12.043

Transcribed Image Text:Apr. 4, 2013 – Researchers at the University of Leeds may have solved a key
puzzle about how objects from space could have kindled life on Earth.
While it is generally accepted that some important ingredients for life came from
meteorites bombarding the early Earth, scientists have not been able to explain
how that inanimate rock transformed into the building blocks of life.
This new study shows how a chemical, similar to one now found in all living cells
and vital for generating the energy that makes something alive, could have been
created when meteorites containing phosphorus minerals landed in hot, acidic
pools of liquids around volcanoes, which were likely to have been common
across the early Earth.
"The mystery of how living organisms sprung out of lifeless rock has long puzzled
scientists, but we think that the unusual phosphorus chemicals we found could
be a precursor to the batteries that now power all life on Earth. But the fact that
it developed simply, in conditions similar to the early Earth, suggests this could
be the missing link between geology and biology," said Dr Terry Kee, from the
University's School of Chemistry, who led the research.
All life on Earth is powered by a process called chemiosmosis, where the
chemical adenosine triphosphate (ATP), the rechargeable chemical 'battery' for
life, is both broken down and re-formed during respiration to release energy
used to drive the reactions of life, or metabolism. The complex enzymes required
for both the creation and break down of ATP are unlikely to have existed on Earth
during the period when life first developed. This led scientists to look for a more
basic chemical with similar properties to ATP, but that does not require enzymes
to transfer energy.
Phosphorus is the key element in ATP, and other fundamental building blocks of
life like DNA, but the form it commonly takes on Earth, phosphorus (V), is largely
insoluble in water and has a low chemical reactivity. The early Earth, however,
was regularly bombarded by meteorites and interstellar dust rich in exotic
minerals, including the far more reactive form of phosphorus, the
iron-nickel-phosphorus mineral schreibersite.
The scientists simulated the impact of such a meteorite with the hot,
volcanically-active, early Earth by placing samples of the Sikhote-Alin meteorite,
an iron meteorite which fell in Siberia in 1947, in acid taken from the Hveradalur
geothermal area in Iceland. The rock was left to react with the acidic fluid in test
tubes incubated by the surrounding hot spring for four days, followed by a
further 30 days at room temperature.
In their analysis of the resulting solution the scientists found the compound
pyrophosphite, a molecular 'cousin' of pyrophosphate -- the part of ATP
responsible for energy transfer. The scientists believe this compound could have
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